Metal-involving halogen bond Ar–I⋯[dz2PtII] in a platinum acetylacetonate complex

CrystEngComm ◽  
2020 ◽  
Vol 22 (3) ◽  
pp. 554-563 ◽  
Author(s):  
Anton V. Rozhkov ◽  
Daniil M. Ivanov ◽  
Alexander S. Novikov ◽  
Ivan V. Ananyev ◽  
Nadezhda A. Bokach ◽  
...  
Keyword(s):  
Experimental Evidence ◽  
Halogen Bond ◽  
Oxidative Addition ◽  
Acetylacetonate Complex ◽  
Formation Step

The observed and confirmed theoretically metal-involving halogen bond Ar–I⋯[dz2PtII] provides experimental evidence favoring a XB formation step upon oxidative addition of ArI to PtII.

Theoretical and Experimental Evidence for SN2 Transition States in Oxidative Addition of Methyl Iodide tocis-[M(CO)2I2]-(M = Rh, Ir)

1996 ◽  
Vol 118 (12) ◽  
pp. 3029-3030 ◽  
Author(s):  
Tim R. Griffin ◽  
David B. Cook ◽  
Anthony Haynes ◽  
Jean M. Pearson ◽  
Donato Monti ◽  
...  
Keyword(s):  
Experimental Evidence ◽  
Methyl Iodide ◽  
Transition States ◽  
Oxidative Addition

How do memory modules differentially contribute to familiarity and recollection?

2019 ◽  
Vol 42 ◽  
Author(s):  
Olya Hakobyan ◽  
Sen Cheng
Keyword(s):  
Recognition Memory ◽  
Experimental Evidence ◽  
Subjective Experience ◽  
Target Article ◽  
Memory Modules ◽  
Familiarity And Recollection ◽  
Memory Contents

Abstract We fully support dissociating the subjective experience from the memory contents in recognition memory, as Bastin et al. posit in the target article. However, having two generic memory modules with qualitatively different functions is not mandatory and is in fact inconsistent with experimental evidence. We propose that quantitative differences in the properties of the memory modules can account for the apparent dissociation of recollection and familiarity along anatomical lines.

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