Electrocatalytic reduction of dioxygen by Mn(iii) meso-tetra(N-methylpyridinium-4-yl)porphyrin in universal buffer

2019 ◽  
Vol 48 (24) ◽  
pp. 8633-8641 ◽  
Author(s):  
Lauren E. Lieske ◽  
Shelby L. Hooe ◽  
Asa W. Nichols ◽  
Charles W. Machan

The electrochemical characterization of manganese(iii) meso-tetra(N-methylpyridinium-4-yl)porphyrin pentachloride via cyclic voltammetry (CV) and UV-vis spectroelectrochemistry (UV-vis SEC) was performed to examine O2 reduction in aqueous conditions.

2009 ◽  
Vol 63 (4) ◽  
pp. 289-292 ◽  
Author(s):  
Lidija Gomidzelovic ◽  
Zvonimir Stankovic ◽  
Zoran Stevic ◽  
Dragana Zivkovic

The Au-In-Sb system belongs to the group of potential candidates for new lead-free solder materials. Therefore, a lot of investigations concerning its phase diagram and thermodynamic, mechanical, physical characteristics are going on at the moment. Having in mind the significance of such materials application in electronics, it is also very important to study their electrochemical characteristics. In order to give such a characterization, the results of cyclic voltammetry measurements for some alloys in the Au-In-Sb system are presented in this paper.


2014 ◽  
Vol 14 (4) ◽  
pp. 75-81 ◽  
Author(s):  
A.P. Nowak ◽  
K. Trzciński ◽  
A. Lisowska-Oleksiak

Abstract New materials obtained by pyrolysis of gelatine (G) and poly(1,2-dimethylsilazane) (PSN) (weight ratio: G/PSN 70/30) at temperatures 700 and 900 °C were characterized by SEM and Raman spectroscopy. The presence of ceramics influences on the cluster size of the materials. Electrochemical tests were performed by cyclic voltammetry and galvanostatic cyclic polarization. The capacity of G/PSN was 464 and 527 mAh/g for materials pyrolysed at 700 and 900 °C. The capacity fading was 1 % after 17th cycle for G/PSN at 900 °C. This value is higher of 185 mAh/g in comparison to capacity of gelatine pyrolysed at the same conditions.


2013 ◽  
Vol 54 (1) ◽  
pp. 85-90 ◽  
Author(s):  
Clementina M.M. Santos ◽  
M. Beatriz Q. Garcia ◽  
Artur M.S. Silva ◽  
René Santus ◽  
Patrice Morlière ◽  
...  

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