scholarly journals The TiO2 topotactic transformation assisted trapping of an atomically dispersed Pt catalyst for low temperature CO oxidation

RSC Advances ◽  
2019 ◽  
Vol 9 (29) ◽  
pp. 16774-16778
Author(s):  
Yunping He ◽  
Xue-Zhi Song ◽  
Feng Ding ◽  
Xiaolan Kang ◽  
Feifei Sun ◽  
...  

Atomically dispersed Pt catalysts are deposited on the rough surface of TiO2, which is synthesized via topotactic transformation from a NH4TiOF3 mesocrystal.

2013 ◽  
Vol 30 (3) ◽  
pp. 598-604 ◽  
Author(s):  
Jung-Hyun Park ◽  
Jun Hee Cho ◽  
Sung Eun Kang ◽  
Kyung Ho Cho ◽  
Tae Woo Lee ◽  
...  

Catalysts ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 1280
Author(s):  
Kailin He ◽  
Qingyue Wang

Metallic Pt sites are imperative in the CO oxidation reaction. Herein, we demonstrate the tuning of Pt sites by treating a Pt catalyst in various reductive atmospheres, influencing the catalyst activities in low-temperature CO oxidation. The H2 pretreatment of Pt clusters at 200 °C decreases the T50 from 208 °C to 183 °C in the 0.1 wt % Pt/TiO2 catalyst. The T50 shows a remarkable improvement using a CO pretreatment, which decreases the T50 further to 135 °C. A comprehensive characterization study reveals the integrated reasons behind this phenomenon: (i) the extent of PtO transition to metallic Pt sites, (ii) the ample surface active oxygen triggered by metallic Pt, (iii) the CO selectively adsorbs on metallic Pt sites which participate in low-temperature CO oxidation, and (iv) the formation of the unstable intermediate such as bicarbonate, contributes together to the enhanced activity of CO pretreated Pt/TiO2.


2008 ◽  
Vol 9 (6) ◽  
pp. 1045-1049 ◽  
Author(s):  
Suying Li ◽  
Gang Liu ◽  
Honglei Lian ◽  
Mingjun Jia ◽  
Guoming Zhao ◽  
...  

2021 ◽  
Author(s):  
R. Rangel ◽  
E. González-A ◽  
A. Solís-García ◽  
T.A. Zepeda ◽  
D.H. Galván ◽  
...  

2021 ◽  
Author(s):  
Dong Jiang ◽  
Yonggang Yao ◽  
Tangyuan Li ◽  
Gang Wan ◽  
Xavier Isidro Pereira-Hernández ◽  
...  

2021 ◽  
Vol 44 (3) ◽  
Author(s):  
Sourav Ghosh ◽  
Sukanya Kundu ◽  
Milan Kanti Naskar

ChemInform ◽  
2010 ◽  
Vol 22 (29) ◽  
pp. no-no
Author(s):  
S. D. GARDNER ◽  
G. B. HOFLUND ◽  
B. T. UPCHURCH ◽  
D. R. SCHRYER ◽  
E. J. KIELIN ◽  
...  

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