Well-defined triblock copolymer/TiO2 composite gel electrolytes for high-performance dye-sensitized solar cells

2019 ◽  
Vol 7 (24) ◽  
pp. 14743-14752 ◽  
Author(s):  
Seung Mo Seo ◽  
Chang Ki Kim ◽  
Hwan Kyu Kim

Two kinds of triblock copolymers (SGT-602 and SGT-604) were prepared and applied to dye-sensitized solar cells (DSSCs). The polymer gel electrolytes with a TiO2 nanofiller achieved comparable efficiencies to liquid-state DSSCs (η: 9.86%), and exhibited excellent long-term device stability under 1 sun illumination at 50 °C.

2012 ◽  
Vol 22 (14) ◽  
pp. 6982 ◽  
Author(s):  
Ying-Chiao Wang ◽  
Kuan-Chieh Huang ◽  
Rui-Xuan Dong ◽  
Chung-Te Liu ◽  
Chun-Chieh Wang ◽  
...  

Polymers ◽  
2020 ◽  
Vol 12 (12) ◽  
pp. 3035
Author(s):  
Jan Lukas Storck ◽  
Marius Dotter ◽  
Sonia Adabra ◽  
Michelle Surjawidjaja ◽  
Bennet Brockhagen ◽  
...  

To overcome the long-term stability problems of dye-sensitized solar cells (DSSC) due to solvent evaporation and leakage, gelling the electrolyte with polymers is an appropriate option. Especially for future applications of textile-based DSSCs, which require cost-effective and environmentally friendly materials, such an improvement of the electrolyte is necessary. Therefore, the temporal progressions of efficiencies and fill factors of non-toxic glass-based DSSCs resulting from different gel electrolytes with poly(ethylene oxide) (PEO) are investigated over 52 days comparatively. Dimethyl sulfoxide (DMSO) proved to be a suitable non-toxic solvent for the proposed gel electrolyte without ionic liquids. A PEO concentration of 17.4 wt% resulted in an optimal compromise with a relatively high efficiency over the entire period. Lower concentrations resulted in higher efficiencies during the first days but in a poorer long-term stability, whereas a higher PEO concentration resulted in an overall lower efficiency. Solvent remaining in the gel electrolyte during application was found advantageous compared to previous solvent evaporation. In contrast to a commercial liquid electrolyte, the long-term stability regarding the efficiency was improved successfully with a similar fill factor and thus equal quality.


RSC Advances ◽  
2016 ◽  
Vol 6 (102) ◽  
pp. 100079-100089 ◽  
Author(s):  
Kaiyue Zhang ◽  
Zijian Cui ◽  
Guangyu Xing ◽  
Yaqing Feng ◽  
Shuxian Meng

The DSSCs based on modified kaolin/PVDF-HFP composite gel electrolyte have excellent efficiency.


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