High oxide ion conductivity in layer-structured Bi4Ti3O12-based ferroelectric ceramics

2019 ◽  
Vol 7 (29) ◽  
pp. 8825-8835 ◽  
Author(s):  
Changbai Long ◽  
Wei Ren ◽  
Yiwen Li ◽  
Laijun Liu ◽  
Yuanhua Xia ◽  
...  

B0.97T0.73Mg0.02 shows high oxide ion conductivity, which is comparable to that of other leading solid oxide electrolyte materials.

2016 ◽  
Vol 120 (33) ◽  
pp. 18452-18461 ◽  
Author(s):  
Kanagaraj Amarsingh Bhabu ◽  
Jayaraman Theerthagiri ◽  
Jagannathan Madhavan ◽  
Thangaraj Balu ◽  
Thanjavur Renganathan Rajasekaran

2006 ◽  
Vol 408-412 ◽  
pp. 507-511 ◽  
Author(s):  
Tatsumi Ishihara ◽  
Masaki Ando ◽  
Makiko Enoki ◽  
Yusaku Takita

2021 ◽  
Vol 2021 ◽  
pp. 1-10
Author(s):  
Shammya Afroze ◽  
Hidayatul Qayyimah Hj Hairul Absah ◽  
Md Sumon Reza ◽  
Mahendra Rao Somalu ◽  
Jun-Young Park ◽  
...  

An excellent oxide ion conductivity with high oxygen transportation of lanthanum silicate apatite at the solid oxide fuel cell (SOFC) can be achieved through the solid-state reaction method. The doped La10Si6−x−0.2AlxZn0.2O27−δ (x = 0.2 and 0.4) materials sintered at 1600°C accomplished crystallinity and crystal structure of apatite-type. The structural and electrochemical characterizations of La10Si6−x−0.2AlxZn0.2O27−δ (x = 0.2 and 0.4) were executed using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX), and electrochemical impedance spectroscopy (EIS) measurements. The total oxide ion conductivities of La10Si6−x−0.2AlxZn0.2O27−δ (x = 0.2 and 0.4) were measured from low to intermediate operating temperature range (450 to 800°C) using electrochemical impedance spectroscopy. Room temperature XRD patterns of La10Si6−x−0.2AlxZn0.2O27−δ (x = 0.2 and 0.4) exhibited La10Si6O27 apatite phase with space group P63/m as the main phase with the minor appearance of La2SiO5 as an impurity phase. The highest total oxide ion conductivity of 3.24 × 10−3 Scm−1 and corresponding activation energy of 0.30 eV at 800°C were obtained for La10Si5.6Al0.2Zn0.2O26.7 which contains a low concentration of Al3+ dopant.


ChemInform ◽  
2006 ◽  
Vol 37 (20) ◽  
Author(s):  
Tatsumi Ishihara ◽  
Masaki Ando ◽  
Makiko Enoki ◽  
Yusaku Takita

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