Coordination distortion induced water adsorption in hydrophobic flexible metal–organic frameworks

2020 ◽  
Vol 56 (64) ◽  
pp. 9106-9109
Author(s):  
Yoshinobu Kamakura ◽  
Arata Hikawa ◽  
Hirofumi Yoshikawa ◽  
Wataru Kosaka ◽  
Hitoshi Miyasaka ◽  
...  

The water-adsorption properties of four isostructural hydrophobic metal-organic frameworks are dependent on the metal species, which was revealed to be caused by coordination distortion around the metal ions.

2015 ◽  
Vol 44 (9) ◽  
pp. 4238-4245 ◽  
Author(s):  
Chuan-Lei Zhang ◽  
Ling Qin ◽  
Zhen-Zhen Shi ◽  
He-Gen Zheng

Diverse structures of metal–organic frameworks induced by different metal ions under solvothermal conditions exhibit different topological characteristics and spectral properties.


2015 ◽  
Vol 3 (5) ◽  
pp. 2057-2064 ◽  
Author(s):  
Nakeun Ko ◽  
Pan Gyu Choi ◽  
Jisu Hong ◽  
Miso Yeo ◽  
Siyoung Sung ◽  
...  

Partial functionalization of the metal–organic framework, MIL-101, with –COOH groups is proven effective for enhancing the water uptake capacity at low pressure.


2020 ◽  
Vol 78 (7) ◽  
pp. 597
Author(s):  
Jinwei Zhang ◽  
Ping Li ◽  
Xinning Zhang ◽  
Xiaojie Ma ◽  
Bo Wang

2021 ◽  
Author(s):  
Yingxue Tu ◽  
Caifen Lei ◽  
Fei Deng ◽  
Yiang Chen ◽  
Ying Wang ◽  
...  

Metal organic frameworks (MOFs) have the potential to boost the undervalued biomedical applications of metal ions. Such endeavor has been hindered by the challenge of how to avoid the (cyto)toxicity...


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