Tuning metal–metal interactions for cooperative small molecule activation

2021 ◽  
Author(s):  
Qiuran Wang ◽  
Sam H. Brooks ◽  
Tianchang Liu ◽  
Neil C. Tomson
Keyword(s):  
Small Molecule ◽  
Small Molecule Activation ◽  
Feature Article ◽  
Metal Interactions ◽  
Recent Advances ◽  
Metal Metal

This Feature Article describes recent advances in the design of multinucleating ligands that support small molecule activation chemistry.

Pillararene-based fluorescent chemosensors: recent advances and perspectives

2017 ◽  
Vol 53 (100) ◽  
pp. 13296-13311 ◽  
Author(s):  
Jin-Fa Chen ◽  
Qi Lin ◽  
You-Ming Zhang ◽  
Hong Yao ◽  
Tai-Bao Wei
Keyword(s):  
Small Molecule ◽  
Biomedical Imaging ◽  
Fluorescent Chemosensor ◽  
Fluorescent Chemosensors ◽  
Biomolecule Detection ◽  
Feature Article ◽  
Ion Sensing ◽  
Recent Advances ◽  
Molecule Recognition ◽  
Supramolecular Aggregates

This feature article summarizes recent research in the pillararene-based fluorescent chemosensor field in terms of ion sensing, small molecule recognition, biomolecule detection, fluorescent supramolecular aggregates, and biomedical imaging.

Recent advances in bioinspired proton-coupled electron transfer

2019 ◽  
Vol 48 (18) ◽  
pp. 5861-5868 ◽  
Author(s):  
Andrea Pannwitz ◽  
Oliver S. Wenger
Keyword(s):  
Electron Transfer ◽  
Solar Energy ◽  
Energy Conversion ◽  
Small Molecule ◽  
Solar Energy Conversion ◽  
Small Molecule Activation ◽  
Reaction Type ◽  
Proton Coupled Electron Transfer ◽  
Recent Advances

Fundamental aspects of PCET continue to attract attention. Understanding this reaction type is desirable for small-molecule activation and solar energy conversion.

scholarly journals Recent advances of group 14 dimetallenes and dimetallynes in bond activation and catalysis

2021 ◽  
Author(s):  
Franziska Hanusch ◽  
Lisa Groll ◽  
Shigeyoshi Inoue
Keyword(s):  
Small Molecule ◽  
Bond Activation ◽  
Small Molecule Activation ◽  
Group 14 ◽  
Recent Advances ◽  
Group 14 Elements ◽  
Catalytic Applications

This minireview highlights the recent advances in small molecule activation and catalytic applications of homonuclear dimetallenes, dimetallynes and interconnected bismetallylenes of heavier group 14 elements.

scholarly journals Small-molecule activation with iron porphyrins using electrons, photons and protons: some recent advances and future strategies

2019 ◽  
Vol 48 (18) ◽  
pp. 5869-5878 ◽  
Author(s):  
Elodie Anxolabéhère-Mallart ◽  
Julien Bonin ◽  
Claire Fave ◽  
Marc Robert
Keyword(s):  
Renewable Energy ◽  
Energy Storage ◽  
Small Molecules ◽  
Small Molecule ◽  
Small Molecule Activation ◽  
Iron Porphyrins ◽  
Direct Production ◽  
Recent Advances ◽  
Molecular Catalysts ◽  
Renewable Energy Storage

Substituted tetraphenyl Fe porphyrins are versatile molecular catalysts for the activation of small molecules (such as O2, H+ or CO2), which could lead to renewable energy storage, the direct production of fuels or new catalytic relevant processes.

Catalytic Reactions by Heterobimetallic Carbonyl Complexes with Polar Metal-Metal Interactions

Synthesis ◽  
2020 ◽  
Author(s):  
Hsien-Cheng Yu ◽  
Neal P Mankad
Keyword(s):  
Precious Metal ◽  
Bond Activation ◽  
Alternative Pathway ◽  
Metal Catalysts ◽  
Catalytic Reactions ◽  
Carbonyl Complexes ◽  
Metal Interactions ◽  
Recent Advances ◽  
Precious Metal Catalysts ◽  
Metal Metal

Heterobinuclear catalysts capable of bimetallic cooperative bond activation provide an alternative pathway to approach discovery of novel and unique reactivity and selectivity in catalytic transformations, complementing more traditional mononuclear precious metal catalysts. This review summarizes recent advances in homogenous catalysis using heterobimetallic carbonyl catalysts with polar metal-metal interactions.

Sign in / Sign up

Export Citation Format

Share Document