scholarly journals Recent advances of group 14 dimetallenes and dimetallynes in bond activation and catalysis

2021 ◽  
Author(s):  
Franziska Hanusch ◽  
Lisa Groll ◽  
Shigeyoshi Inoue
Keyword(s):  
Small Molecule ◽  
Bond Activation ◽  
Small Molecule Activation ◽  
Group 14 ◽  
Recent Advances ◽  
Group 14 Elements ◽  
Catalytic Applications

This minireview highlights the recent advances in small molecule activation and catalytic applications of homonuclear dimetallenes, dimetallynes and interconnected bismetallylenes of heavier group 14 elements.

Tuning metal–metal interactions for cooperative small molecule activation

2021 ◽  
Author(s):  
Qiuran Wang ◽  
Sam H. Brooks ◽  
Tianchang Liu ◽  
Neil C. Tomson
Keyword(s):  
Small Molecule ◽  
Small Molecule Activation ◽  
Feature Article ◽  
Metal Interactions ◽  
Recent Advances ◽  
Metal Metal

This Feature Article describes recent advances in the design of multinucleating ligands that support small molecule activation chemistry.

P–P σ-bond activation by gold(I) coordination

2015 ◽  
Vol 51 (7) ◽  
pp. 1363-1366 ◽  
Author(s):  
Alexander Hinz ◽  
Axel Schulz ◽  
Alexander Villinger
Keyword(s):  
Small Molecule ◽  
Bond Activation ◽  
Small Molecule Activation

Bond activation by gold is of imminent interest with respect to small molecule activation.

Recent advances in bioinspired proton-coupled electron transfer

2019 ◽  
Vol 48 (18) ◽  
pp. 5861-5868 ◽  
Author(s):  
Andrea Pannwitz ◽  
Oliver S. Wenger
Keyword(s):  
Electron Transfer ◽  
Solar Energy ◽  
Energy Conversion ◽  
Small Molecule ◽  
Solar Energy Conversion ◽  
Small Molecule Activation ◽  
Reaction Type ◽  
Proton Coupled Electron Transfer ◽  
Recent Advances

Fundamental aspects of PCET continue to attract attention. Understanding this reaction type is desirable for small-molecule activation and solar energy conversion.

Recent Advances in Reactions of Heteroatom-Centered Radicals

Synthesis ◽  
2017 ◽  
Vol 49 (16) ◽  
pp. 3511-3534 ◽  
Author(s):  
Tsuyoshi Taniguchi
Keyword(s):  
Organic Chemistry ◽  
Synthetic Methods ◽  
Group 14 ◽  
Group 13 ◽  
Radical Chemistry ◽  
New Approaches ◽  
Recent Advances ◽  
Group 14 Elements ◽  
Group 15 ◽  
Group 16

Heteroatom-centered radicals show versatile reactivity and offer useful synthetic methods in organic chemistry. The development of new approaches for forming heteroatom-centered radicals has recently expanded the practicality of radical chemistry for synthesis. This review focuses on recent advances in reactions of representative heteroatom-centered radicals.1 Introduction2 Group 17 Elements: Chlorine and Bromine Radicals3 Group 15 and Group 16 Elements3.1 Nitrogen- and Oxygen-Centered Radicals3.2 Phosphorus- and Sulfur-Centered Radicals3.3 Other Radicals4 Group 14 Elements: Silicon-Centered Radicals5 Group 13 Elements: Boron-Centered Radicals6 Conclusion

scholarly journals Small-molecule activation with iron porphyrins using electrons, photons and protons: some recent advances and future strategies

2019 ◽  
Vol 48 (18) ◽  
pp. 5869-5878 ◽  
Author(s):  
Elodie Anxolabéhère-Mallart ◽  
Julien Bonin ◽  
Claire Fave ◽  
Marc Robert
Keyword(s):  
Renewable Energy ◽  
Energy Storage ◽  
Small Molecules ◽  
Small Molecule ◽  
Small Molecule Activation ◽  
Iron Porphyrins ◽  
Direct Production ◽  
Recent Advances ◽  
Molecular Catalysts ◽  
Renewable Energy Storage

Substituted tetraphenyl Fe porphyrins are versatile molecular catalysts for the activation of small molecules (such as O2, H+ or CO2), which could lead to renewable energy storage, the direct production of fuels or new catalytic relevant processes.

Recent Advances of p53-MDM2 Small Molecule Inhibitors (2011-Present)

2015 ◽  
Vol 22 (5) ◽  
pp. 618-626 ◽  
Author(s):  
Peng-Cheng Lv ◽  
Juan Sun ◽  
Hai-Liang Zhu
Keyword(s):  
Small Molecule ◽  
Small Molecule Inhibitors ◽  
Recent Advances
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