Building an artificial solid electrolyte interphase on spinel lithium manganate for high performance aqueous lithium-ion batteries

2020 ◽  
Vol 49 (24) ◽  
pp. 8136-8142
Author(s):  
Wujie Dong ◽  
Xieyi Huang ◽  
Yan Jin ◽  
Miao Xie ◽  
Wei Zhao ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Lithium Ion Batteries ◽  
High Performance ◽  
Solid Electrolyte Interphase ◽  
Lithium Ion ◽  
Interphase Layer ◽  
Lithium Storage ◽  
Lithium Manganate ◽  
Spinel Lithium Manganate

An artificial solid electrolyte interphase layer using lithium polyacrylate on spinel LiMn2O4 enables fast and durable aqueous lithium storage.

scholarly journals Ceramic-Coated Separator to Enhance Cycling Performance of Lithium-ion Batteries at High Current Density

2021 ◽  
Vol 59 (11) ◽  
pp. 813-820
Author(s):  
Kyusang Cho ◽  
Chandran Balamurugan ◽  
Hana Im ◽  
Hyeong-Jin Kim
Keyword(s):  
Solid Electrolyte ◽  
Lithium Ion Batteries ◽  
High Performance ◽  
Electrochemical Impedance ◽  
High Current Density ◽  
Solid Electrolyte Interphase ◽  
Lithium Ion ◽  
Green Energy ◽  
Cycle Performance ◽  
Polypropylene Separator

Given the global demand for green energy, the battery industry is positioned to be an important future technology. Lithium-ion batteries (LIBs), which are the most widely used battery in the market, are the focus of various research and development efforts, from materials to systems, that seek to improve their performance. The separator is one of the core materials in LIBs and is a significant factor in the lifespan of high-performance batteries. To improve the performance of present LIBs, electrochemical testing and related surface analyses of the separator is essential. In this paper, we prepared a ceramic (Boehmite, γ-AlOOH) coated polypropylene separator and a porous polyimide separator to compare their electrochemical properties with a commercialized polypropylene (PP) separator. The prepared separators were assembled into nickelmanganese-cobalt (NMC) cathode half-cell and full-cell lithium-ion batteries. Their cycling performances were evaluated using differential capacity and electrochemical impedance spectroscopy with ethylene carbonate:dimethylcarbonate (EC:DMC) electrolyte. The ceramic coated polypropylene separator exhibited the best cycle performance at a high 5 C rate, with high ionic conductivity and less resistive solid electrolyte interphase. Also, it was confirmed that a separator solid electrolyte interface (SSEI) layer formed on the separator with cycle repetition, and it was also confirmed that this phenomenon determined the cycle life of the battery depending on the electrolyte.

Artificial Solid Electrolyte Interphase Coating to Reduce Lithium Trapping in Silicon Anode for High Performance Lithium‐Ion Batteries

2019 ◽  
Vol 6 (21) ◽  
pp. 1901187 ◽  
Author(s):  
Qing Ai ◽  
Deping Li ◽  
Jianguang Guo ◽  
Guangmei Hou ◽  
Qing Sun ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Lithium Ion Batteries ◽  
High Performance ◽  
Solid Electrolyte Interphase ◽  
Lithium Ion ◽  
Silicon Anode

scholarly journals Quantifying capacity loss due to solid-electrolyte-interphase layer formation on silicon negative electrodes in lithium-ion batteries

2012 ◽  
Vol 215 ◽  
pp. 145-151 ◽  
Author(s):  
Siva P.V. Nadimpalli ◽  
Vijay A. Sethuraman ◽  
Swapnil Dalavi ◽  
Brett Lucht ◽  
Michael J. Chon ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Lithium Ion Batteries ◽  
Solid Electrolyte Interphase ◽  
Lithium Ion ◽  
Interphase Layer ◽  
Layer Formation ◽  
Capacity Loss ◽  
Negative Electrodes
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