Suppressing Continuous Volume Expansion of Si Nanoparticles by an Artificial Solid Electrolyte Interphase for High-Performance Lithium-Ion Batteries

Author(s):  
Yingzhi Li ◽  
Jiming Lu ◽  
Zhenyu Wang ◽  
Xuyang Wang ◽  
Huimin Yuan ◽  
...  
2020 ◽  
Vol 49 (24) ◽  
pp. 8136-8142
Author(s):  
Wujie Dong ◽  
Xieyi Huang ◽  
Yan Jin ◽  
Miao Xie ◽  
Wei Zhao ◽  
...  

An artificial solid electrolyte interphase layer using lithium polyacrylate on spinel LiMn2O4 enables fast and durable aqueous lithium storage.


2020 ◽  
Vol 2 (8) ◽  
pp. 3222-3230
Author(s):  
Jijun Lu ◽  
Dong Wang ◽  
Junhao Liu ◽  
Guoyu Qian ◽  
Yanan Chen ◽  
...  

The huge volume variation and the unstable solid electrolyte interface (SEI) of silicon (Si) during the lithiation and delithiation process severely obstruct its practical application as lithium-ion battery anodes.


2021 ◽  
Vol 59 (11) ◽  
pp. 813-820
Author(s):  
Kyusang Cho ◽  
Chandran Balamurugan ◽  
Hana Im ◽  
Hyeong-Jin Kim

Given the global demand for green energy, the battery industry is positioned to be an important future technology. Lithium-ion batteries (LIBs), which are the most widely used battery in the market, are the focus of various research and development efforts, from materials to systems, that seek to improve their performance. The separator is one of the core materials in LIBs and is a significant factor in the lifespan of high-performance batteries. To improve the performance of present LIBs, electrochemical testing and related surface analyses of the separator is essential. In this paper, we prepared a ceramic (Boehmite, γ-AlOOH) coated polypropylene separator and a porous polyimide separator to compare their electrochemical properties with a commercialized polypropylene (PP) separator. The prepared separators were assembled into nickelmanganese-cobalt (NMC) cathode half-cell and full-cell lithium-ion batteries. Their cycling performances were evaluated using differential capacity and electrochemical impedance spectroscopy with ethylene carbonate:dimethylcarbonate (EC:DMC) electrolyte. The ceramic coated polypropylene separator exhibited the best cycle performance at a high 5 C rate, with high ionic conductivity and less resistive solid electrolyte interphase. Also, it was confirmed that a separator solid electrolyte interface (SSEI) layer formed on the separator with cycle repetition, and it was also confirmed that this phenomenon determined the cycle life of the battery depending on the electrolyte.


2019 ◽  
Vol 6 (21) ◽  
pp. 1901187 ◽  
Author(s):  
Qing Ai ◽  
Deping Li ◽  
Jianguang Guo ◽  
Guangmei Hou ◽  
Qing Sun ◽  
...  

Author(s):  
Huitian Liu ◽  
Xu Liu ◽  
Zhaolin Liu ◽  
Junyan Tao ◽  
Xiaoqian Dai ◽  
...  

Engineering of graphite@Si/carbon composites is considered as an effective strategy to surmount the shortcomings of low conductivity and large volume expansion of bare Si anode materials for lithium-ion batteries. Nevertheless,...


Sign in / Sign up

Export Citation Format

Share Document