One-step introduction of terminal sulfonic groups into a proton-conducting metal–organic framework by concerted deprotonation–metalation–hydrolysis reaction

2020 ◽  
Vol 49 (29) ◽  
pp. 9953-9956
Author(s):  
Monika Szufla ◽  
Kornel Roztocki ◽  
Anna Krawczuk ◽  
Dariusz Matoga

A one-step strategy for introducing terminal sulfonic groups from a hydrolysable precursor is demonstrated for a proton-conducting metal–organic framework.

RSC Advances ◽  
2021 ◽  
Vol 11 (19) ◽  
pp. 11495-11499
Author(s):  
Lu Feng ◽  
Tian-Yu Zeng ◽  
Hao-Bo Hou ◽  
Hong Zhou ◽  
Jian Tian

A water-mediated proton-conducting Eu(iii)-MOF has been synthesized, which provides a stable proton transport channel that was confirmed by theoretical calculation.


2015 ◽  
Vol 21 (33) ◽  
pp. 11894-11898 ◽  
Author(s):  
En-Long Zhou ◽  
Chao Qin ◽  
Peng Huang ◽  
Xin-Long Wang ◽  
Wei-Chao Chen ◽  
...  

2016 ◽  
Vol 120 (49) ◽  
pp. 28374-28374 ◽  
Author(s):  
P. G. M. Mileo ◽  
S. Devautour-Vinot ◽  
G. Mouchaham ◽  
F. Faucher ◽  
A. Vimont ◽  
...  

2015 ◽  
Vol 51 (36) ◽  
pp. 7637-7640 ◽  
Author(s):  
Dariusz Matoga ◽  
Marcin Oszajca ◽  
Marcin Molenda

A high proton-conducting metal–organic framework (PCMOF) is prepared for the first time by economical and environmentally-friendly mechanochemistry.


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