Fabrication and Evaluation of Bimetallic Materials for Removal of Cr6+

Adsorption technology is an effective way for removal of heavy metals ions and other organic pollutants in water treatment. In recent years, bimetallic adsorbents with high performance and low cost have attracted more and more attention. In this study, nano zero valent iron was prepared. On this basis, Fe/Cu Bimetallic materials were prepared. The effects of Cu conversion, initial concentration, time, and pH value on Cr6+ removal rate and amount were systematically tested. The results show that under the conditions of initial concentration (50mg/L), time (60min) and pH (3), the Fe/Cu material with copper conversion of 3% has the best effect on the removal of Cr6+ in wastewater. Thus, this study is expected to provide important reference data for the effective removal of Cr6+ in water.

Combined Spectroscopic and Computational Study of Nitrobenzene Activation on Non-Noble Metals-Based Mono- and Bimetallic Catalysts

In this paper, substituted anilines are industrially obtained by direct hydrogenation of nitroaromatic compounds with molecular H2 using metals as catalysts. Previous theoretical studies proposed that the mechanism of the reaction depends on the nature of the metal used as a catalyst, and that rationally designed bimetallic materials might show improved catalytic performance. Herein, we present IR spectroscopic studies of nitrobenzene interactions with monometallic Ni/SiO2, Cu/SiO2 and Pd/SiO2, and with bimetallic CuNi/SiO2 and CuPd/SiO2 catalysts, both in the absence and presence of H2, combined with density functional theory (DFT) calculations on selected bimetallic NiCu(111) and PdCu(111) models. The results obtained experimentally confirm that the reaction mechanism on non-noble metals such as Ni proceeds through N-O bond dissociation, generating nitrosobenzene intermediates, while, on noble metals, such as Pd, H-attack is necessary to activate the NO bond. Moreover, a bimetallic CuPd/SiO2 catalyst with a Pd enriched surface is prepared that exhibits an enhanced H2 dissociation ability and a particular reactivity at the boundary between the two metals.

Special Features of Formation of the High Damping State in Bimetallic Structural Materials Obtained by Explosion Welding

Special features of the high-damping state formation in bimetallic materials produced by explosion welding have been studied. High-damping Mn-Cu alloy was used for the damping base of the bimetallic composite and high–strength steel (grade: 30HGSA) was used to form the coating layer. The effect of planar tensile stresses (observed in the damping component of the bimetal and caused by valuable difference between coefficients of thermal expansion of components of the bimetal) is discussed. Damping properties of bimetallic materials were found to be comparable with damping characteristics of monolithic high damping alloys. High-strength steel provides high-strength characteristics of the surface layer of the bimetal, where the strength level reaches 1100MPa and the hardness is equal to 50 HRC. Obtained combination of high damping and high strength in developed bimetallic materials provides real chance for practical application of these materials in industry.