Crosslinking modification of a porous metal–organic framework (UIO-66) and hydrogen storage properties

2020 ◽  
Vol 44 (26) ◽  
pp. 11164-11171
Author(s):  
Zhuo Wang ◽  
Jin Liu ◽  
Zhen Li ◽  
Xianbiao Wang ◽  
Ping Wang ◽  
...  

A crosslinked MOF material UIO-66-DETA-CL is synthesized, and has stronger thermal performance and hydrogen storage performance than before crosslinking.

2009 ◽  
Vol 48 (14) ◽  
pp. 6559-6565 ◽  
Author(s):  
Stephanie E. Wenzel ◽  
Michael Fischer ◽  
Frank Hoffmann ◽  
Michael Fröba

2016 ◽  
Vol 41 (28) ◽  
pp. 12167-12174 ◽  
Author(s):  
Zeynel Ozturk ◽  
Dursun Ali Kose ◽  
Zarife Sibel Sahin ◽  
Goksel Ozkan ◽  
Abdurrahman Asan

2019 ◽  
Vol 7 (10) ◽  
pp. 5277-5287 ◽  
Author(s):  
Meijia Liu ◽  
Xuezhang Xiao ◽  
Shuchun Zhao ◽  
Man Chen ◽  
Jianfeng Mao ◽  
...  

Catalytic doping is important for enhancing the hydrogen storage performance of metal hydrides, but it is challenging to develop a single catalyst to enhance both hydrogen desorption and absorption to a certain degree.


Metals ◽  
2020 ◽  
Vol 10 (12) ◽  
pp. 1574
Author(s):  
Ruochen Shen ◽  
Chaohui Pu ◽  
Xiaoou Xu ◽  
Youpeng Xu ◽  
Zhilin Li ◽  
...  

The research aims to study the effect of adding mischmetal (Mm) to the TiFe0.86Mn0.07Co0.07 alloy on its hydrogen storage performance and cyclic stability. The results show that TiFe0.86Mn0.07Co0.07 + x% Mm (x = 0,4,6,8) alloys can be easily activated. The hydrogen absorption capacity of TiFe0.86Mn0.07Co0.07 + 4% Mm reaches 1.76 wt% (mass fraction) at 298 K. With the increase of Mm addition, the hydrogen storage capacity decreases slightly. Furthermore, after 40 absorption and desorption cycles in hydrogen containing 250 ppm O2, the alloy still has 36% of its initial hydrogen storage capacity, and the alloy can recover 93% of its hydrogen storage capacity through heat treatment.


Sign in / Sign up

Export Citation Format

Share Document