Metal-Free Photocatalytic Hydrosilylation of Olefins in the Presence of Photoinitiator

New Journal of Chemistry ◽

10.1039/d0nj06075e ◽

2021 ◽

Author(s):

Zehao Yu ◽

Zinan Dai ◽

Ying Bai ◽

Jiayun Li ◽

Yan Yan ◽

...

Keyword(s):

Free Radical ◽

Metal Free ◽

Radical Type ◽

Cyclic Alkenes

A convenient metal-free photocatalytic hydrosilylation of variety of linear and cyclic alkenes have been investigated. It was found that the free radical type photoinitiator Irgacure 2959 had a better effect...

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Deaminative carbonylative thioesterification of activated alkylamines with thiophenols under transition-metal-free conditions

Organic Chemistry Frontiers ◽

10.1039/d0qo01479f ◽

2021 ◽

Author(s):

Fengqian Zhao ◽

Xiao-Feng Wu

Keyword(s):

Free Radical ◽

Transition Metal ◽

Metal Free

A transition-metal-free radical carbonylation of activated alkylamines with thiophenols has been successfully developed. Various thioesters were selectively produced with moderate to good yields.

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Metal–Free Radical Thiocyanatosulfonation of Terminal Alkynes in Aqueous Medium

Organic Letters ◽

10.1021/acs.orglett.1c00820 ◽

2021 ◽

Author(s):

Mingmei Zhang ◽

Xianghua Zeng

Keyword(s):

Free Radical ◽

Aqueous Medium ◽

Terminal Alkynes ◽

Metal Free

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A metal-free radical cascade reaction of phosphine oxides with 2-aryloxy phenylacetylenes to assemble diphosphonyl xanthene derivatives

Organic & Biomolecular Chemistry ◽

10.1039/d1ob01045j ◽

2021 ◽

Author(s):

Tao Fan ◽

Yan Liu ◽

Caina Jiang ◽

Yanli Xu ◽

Yan-Yan Chen

Keyword(s):

Free Radical ◽

Transition Metal ◽

Cascade Reaction ◽

Phosphine Oxides ◽

Metal Free ◽

Mild Conditions ◽

Xanthene Derivatives ◽

Reaction Proceeds ◽

Radical Cascade

A radical cascade reaction of 2-aryloxy phenylacetylene with phosphine oxides promoted by K2S2O8 was developed, provided diphosphonyl xanthenes as products. This reaction proceeds under transition metal-free and mild conditions with...

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Metal-Free Cascade Methylation/Cyclization of N-Alkyl-N-methacryloylbenzamides with Dicumyl Peroxide

Synlett ◽

10.1055/s-0036-1591522 ◽

2017 ◽

Vol 29 (05) ◽

pp. 617-620 ◽

Cited By ~ 6

Author(s):

Yan-Ning Niu ◽

Xiao-Feng Xia ◽

Yuan Yuan

Keyword(s):

Free Radical ◽

Dicumyl Peroxide ◽

Metal Free ◽

Wide Range ◽

Radical Cascade ◽

Convenient Access

A metal-free radical cascade methylation/cyclization of a wide range of N-alkyl-N-methacryloylbenzamides by using dicumyl peroxide as the methylating reagent provides a convenient access to a series of methylated isoquinoline-1,3-diones in moderate yields.

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Synthesis of Polychloromethyl-Containing Indolines via Metal-Free Radical Arylpolychloromethylation of Unactivated Alkenes

Chinese Journal of Organic Chemistry ◽

10.6023/cjoc201901047 ◽

2019 ◽

Vol 39 (6) ◽

pp. 1727 ◽

Cited By ~ 1

Author(s):

Wenlan Li ◽

Yitong Sun ◽

Yongchao Yao ◽

Ying Xu ◽

Peng Li ◽

...

Keyword(s):

Free Radical ◽

Metal Free

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Metal-free radical cascade dichloromethylation of activated alkenes using CH2Cl2: highly selective activation of the C–H bond

RSC Advances ◽

10.1039/c4ra12032a ◽

2014 ◽

Vol 4 (110) ◽

pp. 64855-64859 ◽

Cited By ~ 28

Author(s):

Yunfei Tian ◽

Zhong-Quan Liu

Keyword(s):

Free Radical ◽

Dicumyl Peroxide ◽

Cascade Process ◽

Selective Activation ◽

Metal Free ◽

Efficient Access ◽

Radical Cascade

A dicumyl peroxide-initiated highly selective activation of the (sp3)C–H bond in dichloromethane (DCM, CH2Cl2) has been achieved, which allows efficient access to dichloronated oxindoles via a free-radical cascade process.

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