Polyolefin graft copolymers through a ring-opening metathesis grafting through approach

2021 ◽  
Vol 12 (14) ◽  
pp. 2075-2083
Author(s):  
Huiqun Wang ◽  
Sebla Onbulak ◽  
Steven Weigand ◽  
Frank S. Bates ◽  
Marc A. Hillmyer

A series of polyethylene-g-atactic polypropylene graft copolymers were synthesized by grafting through copolymerization of a cyclooctene terminated aPP macromonomer with cyclooctene monomer and subsequent hydrogenation.


1992 ◽  
Vol 64 (1) ◽  
pp. 113-120 ◽  
Author(s):  
Eric J. Goethals ◽  
Veska Toncheva ◽  
Fried'l Hosteaux ◽  
Saskia Walraedt ◽  
Ronny de Clercq


2009 ◽  
Vol 51 (11-12) ◽  
pp. 1210-1217 ◽  
Author(s):  
Shigeki Ohno ◽  
Alper Nese ◽  
Brian Cusick ◽  
Tomasz Kowalewski ◽  
Krzysztof Matyjaszewski


2020 ◽  
Vol 11 (3) ◽  
pp. 682-686 ◽  
Author(s):  
Chunyang Bao ◽  
Xiaoling Xu ◽  
Jing Chen ◽  
Qiang Zhang

Lipase–poly(HEAA) conjugates act as initiators and catalysts simultaneously for the eROP of ε-CL, forming biodegradable conjugates with amphiphilic graft copolymers.



2020 ◽  
Vol 11 (42) ◽  
pp. 6847-6852
Author(s):  
Jungyeon Kim ◽  
Christopher Waldron ◽  
Beatrice Cattoz ◽  
C. Remzi Becer

An inimer-like structure that consists of a 2-oxazoline ring for cationic ring opening polymerisation and a typical alpha-bromo ester initiator for Cu-RDRP has been synthesised using ε-Caprolactone as the starting material.



2008 ◽  
Vol 86 (6) ◽  
pp. 570-578 ◽  
Author(s):  
Sophie Nguyen

The use of the poly(3-hydroxyalkanoates) in copolymer synthesis has received much interest, as the microbial polyester segments can bring interesting properties, such as biodegradability and biocompatibility. The synthesis, properties, and applications of graft copolymers containing poly(3-hydroxyalkanoates) as main chain or branches are reviewed here, with emphasis on the different preparation methods, which fit into the three main synthesis strategies of graft copolymers: “grafting onto”, “grafting from”, and “grafting through” or macromonomer methods.Key words: poly(3-hydroxyalkanoates), graft copolymer, synthesis, properties, applications.



2013 ◽  
Vol 4 (13) ◽  
pp. 3705 ◽  
Author(s):  
Fanny Coumes ◽  
Vincent Darcos ◽  
Dominique Domurado ◽  
Suming Li ◽  
Jean Coudane


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