Carbon monoxide formation from trimethylamine-boranecarboxylate: DFT studies of SNi and chelotropic mechanisms
According to a DFT model, CO is formed from trimethylamine boranecarboxylate, a carbon monoxide releasing molecular pro-drug (CORM), via initial SNi subsitution followed by chelotropic fragmentation of the resulting cyclic carboxyborane anion.
2000 ◽
Vol 91
(2)
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pp. 446-451
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2019 ◽
Vol 7
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2016 ◽
Vol 23
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pp. 922-926