scholarly journals Carbon monoxide formation from trimethylamine-boranecarboxylate: DFT studies of SNi and chelotropic mechanisms

RSC Advances ◽  
2020 ◽  
Vol 10 (27) ◽  
pp. 16038-16044 ◽  
Author(s):  
John W. Keller ◽  
Theppawut I. Ayudhya ◽  
Nin N. Dingra

According to a DFT model, CO is formed from trimethylamine boranecarboxylate, a carbon monoxide releasing molecular pro-drug (CORM), via initial SNi subsitution followed by chelotropic fragmentation of the resulting cyclic carboxyborane anion.

Author(s):  
Wirya Sarwana ◽  
Akihiko Anzai ◽  
Daichi Takami ◽  
Akira Yamamoto ◽  
Hisao Yoshida

Photocatalytic steam reforming of methane (PSRM) has been studied as an attractive method to produce hydrogen by utilizing photoenergy like solar energy around room temperature with metal-loaded photocatalysts, where methane...


1954 ◽  
Author(s):  
G.J. Alkire ◽  
R.D. Tillson ◽  
H.J. Anderson ◽  
J.L. Carroll

Author(s):  
Sylwia Stegenta-Dąbrowska ◽  
Grzegorz Drabczyński ◽  
Karolina Sobieraj ◽  
Jacek A. Koziel ◽  
Andrzej Białowiec

1970 ◽  
Vol 16 (6) ◽  
pp. 237-239 ◽  
Author(s):  
W. J. Wiegand ◽  
M. C. Fowler ◽  
J. A. Benda

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