scholarly journals Trioxatriangulenium (TOTA+) as a robust carbon-based Lewis acid in frustrated Lewis pair chemistry

2021 ◽  
Author(s):  
Aslam C. Shaikh ◽  
José M. Veleta ◽  
Jules Moutet ◽  
Thomas L. Gianetti
Keyword(s):  
Lewis Acid ◽  
Bond Cleavage ◽  
Stable Carbon ◽  
Lewis Bases ◽  
Frustrated Lewis Pair ◽  
Carbon Based

Frustration at carbon! Herein, we present a frustrated Lewis pair system derived from a water stable carbon-based Lewis acid, trioxatriangulene (TOTA+), and a variety of Lewis bases, which successfully promotes bond cleavage and molecule fixation.

scholarly journals H2 activation by hydrogenase-inspired NiFe catalyst using frustrated Lewis pair: effect of buffer and halide ion in the heterolytic H–H bond cleavage

RSC Advances ◽  
2021 ◽  
Vol 11 (45) ◽  
pp. 28420-28432
Author(s):  
Miho Isegawa ◽  
Takahiro Matsumoto ◽  
Seiji Ogo
Keyword(s):  
Fossil Fuels ◽  
Bond Cleavage ◽  
Clean Fuel ◽  
Frustrated Lewis Pair

Hydrogen is a clean fuel alternative to fossil fuels, and it is vital to develop catalysts for its efficient activation and production.

Carbon Monoxide Bond Cleavage Mediated by an Intramolecular Frustrated Lewis Pair: Access to New B/N Heterocycles via Selective Incorporation of Single Carbon Atoms

2021 ◽  
Author(s):  
Clemens Krempner ◽  
Chamila Manankandayalage ◽  
Daniel K Unruh
Keyword(s):  
Carbon Monoxide ◽  
Bond Cleavage ◽  
Frustrated Lewis Pair ◽  
Selective Incorporation

Utilizing an intramolecular frustrated Lewis pair (FLP) decorated with a strongly donating guanidino moiety enabled the formation of a thermally remarkably stable FLP-CO adduct, which at 120°C underwent CO migration...

Living polymerization of naturally renewable butyrolactone-based vinylidenes mediated by a frustrated Lewis pair

2021 ◽  
Vol 12 (38) ◽  
pp. 5548-5555
Author(s):  
Yun Bai ◽  
Huaiyu Wang ◽  
Jianghua He ◽  
Yuetao Zhang
Keyword(s):  
Lewis Acid ◽  
Living Polymerization ◽  
Controlled Polymerization ◽  
Frustrated Lewis Pair

The frustrated Lewis pair composed of an organophosphorus(iii) superbase and a bulky organoaluminum Lewis acid promoted the living/controlled polymerization of naturally renewable butyrolactone-based vinylidenes.

scholarly journals Sc3N@Ih-C80 as a novel Lewis acid to trap abnormal N-heterocyclic carbenes: the unprecedented formation of a singly bonded [6,6,6]-adduct

2016 ◽  
Vol 7 (3) ◽  
pp. 2331-2334 ◽  
Author(s):  
Muqing Chen ◽  
Lipiao Bao ◽  
Min Ai ◽  
Wangqiang Shen ◽  
Xing Lu
Keyword(s):  
Lewis Acid ◽  
Heterocyclic Carbenes ◽  
Acid Base ◽  
Base Pairs ◽  
Endohedral Metallofullerenes ◽  
Carbon Based

An unprecedented singly bonded [6,6,6]-adduct with an abnormal N-heterocyclic carbene structure, represents the first example of carbon-based Lewis acid–base pairs based on endohedral metallofullerenes.

Efficient and stable carbon-based perovskite solar cells enabled by the inorganic interface of CuSCN and carbon nanotubes

2019 ◽  
Vol 7 (19) ◽  
pp. 12236-12243 ◽  
Author(s):  
Xin Wu ◽  
Liqiang Xie ◽  
Kebin Lin ◽  
Jianxun Lu ◽  
Kexiang Wang ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Stable Carbon ◽  
Carbon Based

The inorganic CuSCN interlayer makes carbon-based perovskite solar cells more efficient and stable.

Developing carbon Lewis base/boron Lewis acid frustrated Lewis pair chemistry derived from conjugated dienamines

Tetrahedron ◽  
2019 ◽  
Vol 75 (5) ◽  
pp. 571-579 ◽  
Author(s):  
Jennifer Möricke ◽  
Florian Rehwinkel ◽  
Tobias Danelzik ◽  
Constantin G. Daniliuc ◽  
Birgit Wibbeling ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Lewis Base ◽  
Frustrated Lewis Pair
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