The wormlike micelles formed using an ionic liquid surfactant and polar organic solvents at low temperature without additives and their lubricant properties

Soft Matter ◽  
2021 ◽  
Author(s):  
Huijiao Cao ◽  
Wenlin Xu ◽  
Xia Guo

Wormlike micelles (or reverse wormlike micelles) are flexible cylindrical chains that are normally formed in water (or a nonpolar organic solvent) at 25.0 °C or above; the formation of wormlike micelles at lower temperatures is rare.

2016 ◽  
Vol 18 (36) ◽  
pp. 25458-25464 ◽  
Author(s):  
Luis Aguilera ◽  
Johan Scheers ◽  
Aleksandar Matic

We investigate Li+ coordination in mixed electrolytes based on ionic liquids (ILs) and organic solvents and its relation with the macroscopic properties such as phase behaviour and ionic conductivity.


2015 ◽  
Vol 11 ◽  
pp. 1632-1638 ◽  
Author(s):  
Maximilian Koy ◽  
Hagen J Altmann ◽  
Benjamin Autenrieth ◽  
Wolfgang Frey ◽  
Michael R Buchmeiser

The novel dicationic metathesis catalyst [(RuCl2(H2ITapMe2)(=CH–2-(2-PrO)-C6H4))2+ (OTf−)2] (Ru-2, H2ITapMe2 = 1,3-bis(2’,6’-dimethyl-4’-trimethylammoniumphenyl)-4,5-dihydroimidazol-2-ylidene, OTf− = CF3SO3 −) based on a dicationic N-heterocyclic carbene (NHC) ligand was prepared. The reactivity was tested in ring opening metathesis polymerization (ROMP) under biphasic conditions using a nonpolar organic solvent (toluene) and the ionic liquid (IL) 1-butyl-2,3-dimethylimidazolium tetrafluoroborate [BDMIM+][BF4 −]. The structure of Ru-2 was confirmed by single crystal X-ray analysis.


1982 ◽  
Vol 36 (4) ◽  
pp. 430-435 ◽  
Author(s):  
David K. Lavallee ◽  
Thomas J. McDonough ◽  
Lisa Cioffi

As part of an ongoing study of the chemistry and properties of N-methylporphyrins and their metal complexes, we have observed that the excitation and emission spectra of N-methyltetraphenylporphyrin and N-methyltetra( p-sulfophenyl)porphyrin and their zinc complexes closely resemble corresponding spectra of chlorophyll a. We have characterized fluorescence spectra for these species in a variety of solvents commonly used for quantitative determination of chlorophylls. Quantum yields for the N-methylporphyrins are lower by approximately a factor of 10 than yields for chlorophyll a in such solvents as acetone, ethanol, and mixed aqueous/organic solvent systems. The yields are quite sufficient, however, for these species to be used as fluorescence standards. Solution of N-methylporphyrins are stable and the compounds can be inexpensively synthesized in high purity. The tetra( p-sulfophenyl) species are soluble in aqueous and highly polar organic solvents, whereas the tetraphenyl species are soluble in nonpolar organic solvents.


2011 ◽  
Vol 312 ◽  
pp. 31-36 ◽  
Author(s):  
Yingqian Ren ◽  
Haizhou Shui ◽  
Changjun Peng ◽  
Honglai Liu ◽  
Ying Hu

2021 ◽  
Vol MA2021-02 (59) ◽  
pp. 1759-1759
Author(s):  
Seungmin Oh ◽  
Michael Keating ◽  
Elizabeth J. Biddinger

2015 ◽  
Vol 7 (17) ◽  
pp. 8979-8983 ◽  
Author(s):  
W. Jeffrey Horne ◽  
Mary A. Andrews ◽  
Kelsey L. Terrill ◽  
Spenser S. Hayward ◽  
Jeannie Marshall ◽  
...  

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