The critical effect of water content in the electrolyte on the reversible electrochemical performance of Zn–VPO4F cells

2020 ◽  
Vol 8 (17) ◽  
pp. 8262-8267 ◽  
Author(s):  
Hooman Yaghoobnejad Asl ◽  
Shyam Sharma ◽  
Arumugam Manthiram

The critical role of water as a source of H+ working ions and reactive species in the Zn–VPO4F electrochemical system with an ionic liquid electrolyte.

2018 ◽  
Vol 2018 ◽  
pp. 1-7
Author(s):  
Jie Tang ◽  
DongLiang Lv ◽  
CunYing Xu ◽  
YiXin Hua ◽  
QiBo Zhang ◽  
...  

The electrodeposition of tin from SnO in ionic liquid 1-butyl-3-methylimidazolium hydrogen sulfate ([Bmim]HSO4) in the presence of water at different cathodic potential was investigated. With the addition of water to [Bmim]HSO4ionic liquid, the electrochemical window of the electrolyte decreases and the reduction potential of Sn(II) positively shifts. The water content of ionic liquid electrolyte has a distinct effect on morphology of the deposits. As water content increased from 0 to 50% (v/v), the morphology of deposits varies from granular to hexagonal rod-like, then to hollow tubular, and finally to wire-like. The XRD phase analysis showed that both Sn and CuSn alloys were deposited in ionic liquid/water mixtures. However, in dried ionic liquids only Cu3Sn was obtained, surprisingly. The difference in the structure might be attributed to the various interactions of the ions with the Cu substrate. In addition, the deposition potential was found to play a significant role in the morphology of deposits.


2019 ◽  
Vol 845 ◽  
pp. 66-71
Author(s):  
Kazuki Yamaguchi ◽  
Hiroyuki Usui ◽  
Yasuhiro Domi ◽  
Haruka Nishida ◽  
Takuro Komura ◽  
...  

2018 ◽  
Vol 47 (11) ◽  
pp. 1416-1419 ◽  
Author(s):  
Kazuki Yamaguchi ◽  
Yasuhiro Domi ◽  
Hiroyuki Usui ◽  
Ayumu Ueno ◽  
Takuro Komura ◽  
...  

Nano Letters ◽  
2020 ◽  
Vol 20 (10) ◽  
pp. 7011-7019
Author(s):  
Killian Stokes ◽  
Tadhg Kennedy ◽  
Guk-Tae Kim ◽  
Hugh Geaney ◽  
Dylan Storan ◽  
...  

2017 ◽  
Vol 2 (3) ◽  
pp. 689-693 ◽  
Author(s):  
Michael L. Agiorgousis ◽  
Yi-Yang Sun ◽  
Shengbai Zhang

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