Single-atom Ru anchored in nitrogen-doped MXene (Ti3C2Tx) as an efficient catalyst for the hydrogen evolution reaction at all pH values

2020 ◽  
Vol 8 (46) ◽  
pp. 24710-24717
Author(s):  
Haigang Liu ◽  
Zhe Hu ◽  
Qinglei Liu ◽  
Peng Sun ◽  
Yongfei Wang ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Hydrogen Generation ◽  
Single Atom ◽  
Efficient Catalyst ◽  
Nitrogen Doped ◽  
Ph Values ◽  
Theoretical Predictions ◽  
Better Than

A catalyst consisting of single-atom Ru sites supported on an N-MXene (Ti3C2Tx) was developed for pH-universal hydrogen generation based on theoretical predictions, whose performances are comparable to and better than those of Pt/C.

Low-ruthenium-content NiRu nanoalloys encapsulated in nitrogen-doped carbon as highly efficient and pH-universal electrocatalysts for the hydrogen evolution reaction

2018 ◽  
Vol 6 (4) ◽  
pp. 1376-1381 ◽  
Author(s):  
You Xu ◽  
Shuli Yin ◽  
Chunjie Li ◽  
Kai Deng ◽  
Hairong Xue ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Efficient Catalyst ◽  
Nitrogen Doped ◽  
Highly Efficient ◽  
Wide Ph Range ◽  
Ph Range ◽  
Nitrogen Doped Carbon

A NiRu@N–C hybrid is fabricated and tested as an efficient catalyst for the hydrogen evolution reaction in a wide pH range.

Rational design of atomically dispersed nickel active sites in β-Mo2C for the hydrogen evolution reaction at all pH values

2018 ◽  
Vol 54 (71) ◽  
pp. 9901-9904 ◽  
Author(s):  
Ting Ouyang ◽  
An-Na Chen ◽  
Zhen-Zhao He ◽  
Zhao-Qing Liu ◽  
Yexiang Tong
Keyword(s):  
Synergistic Effect ◽  
Electrochemical Properties ◽  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Active Sites ◽  
Rational Design ◽  
Efficient Catalyst ◽  
Ph Values ◽  
Ni Species

Atomically dispersed Ni in β-Mo2C (Ni/β-Mo2C) is designed as an efficient catalyst for the HER at all pH values. The remarkable electrochemical properties of Ni/β-Mo2C are mainly attributed to the synergistic effect between atomically dispersed Ni species and β-Mo2C.

Nitrogen-doped Sr2Fe1.5Mo0.5O6-δ Perovskite as Efficient and Stable Catalysts for Hydrogen Evolution Reaction

2021 ◽  
pp. 100695
Author(s):  
Jianxiong Gao ◽  
Yajing Zhang ◽  
Xingkun Wang ◽  
Lujian Jia ◽  
Heqing Jiang ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Nitrogen Doped

scholarly journals Electronic metal–support interaction modulates single-atom platinum catalysis for hydrogen evolution reaction

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Yi Shi ◽  
Zhi-Rui Ma ◽  
Yi-Ying Xiao ◽  
Yun-Chao Yin ◽  
Wen-Mao Huang ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Structure Activity Relationship ◽  
Atomic Level ◽  
Single Atom ◽  
Activity Relationship ◽  
Support Interaction ◽  
Structure Activity ◽  
Metal Support Interaction ◽  
Metal Support

AbstractTuning metal–support interaction has been considered as an effective approach to modulate the electronic structure and catalytic activity of supported metal catalysts. At the atomic level, the understanding of the structure–activity relationship still remains obscure in heterogeneous catalysis, such as the conversion of water (alkaline) or hydronium ions (acid) to hydrogen (hydrogen evolution reaction, HER). Here, we reveal that the fine control over the oxidation states of single-atom Pt catalysts through electronic metal–support interaction significantly modulates the catalytic activities in either acidic or alkaline HER. Combined with detailed spectroscopic and electrochemical characterizations, the structure–activity relationship is established by correlating the acidic/alkaline HER activity with the average oxidation state of single-atom Pt and the Pt–H/Pt–OH interaction. This study sheds light on the atomic-level mechanistic understanding of acidic and alkaline HER, and further provides guidelines for the rational design of high-performance single-atom catalysts.

Cobalt phthalocyanine as an efficient catalyst for hydrogen evolution reaction

2021 ◽  
Author(s):  
Lifang Chen ◽  
Rizwan Ur Rehman Sagar ◽  
Jun Chen ◽  
Juan Liu ◽  
Sehrish Aslam ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Cobalt Phthalocyanine ◽  
Efficient Catalyst
Sign in / Sign up

Export Citation Format

Share Document