N-doped porous carbon spheres as metal-free electrocatalyst for oxygen reduction reaction

Author(s):  
Guangyuan Ren ◽  
Shaoqing Chen ◽  
Junxian Zhang ◽  
Nianji Zhang ◽  
Chuanlai Jiao ◽  
...  

The exploration of efficient oxygen reduction reaction (ORR) electrocatalysts with low-cost and facile process is crucial for the commercialization of fuel cells and metal-air batteries. Herein, we demonstrate a template-free...

2021 ◽  
Vol 9 (15) ◽  
pp. 9644-9654
Author(s):  
Halima Begum ◽  
Mohammad Shamsuddin Ahmed ◽  
Seunghun Jung

Introducing abundant active sites and improving their activity are two critical considerations for designing metal-free nitrogenous electrocatalysts for the oxygen reduction reaction (ORR) in energy conversion devices such as metal–air batteries and fuel cells.


2021 ◽  
Author(s):  
Xian-Kai Wan ◽  
Gabor Samjeské ◽  
Hirosuke Matsui ◽  
Chaoqi Chen ◽  
Satoshi Muratsugu ◽  
...  

Small-sized Pt–Ni nanoparticles were synthesized into hollow porous carbon spheres (HPCS) under molecule assistance. Pt–Ni nanoparticle/HPCS prepared in presence of 2,2′-Dipyridylamine showed excellent oxygen reduction reaction activity/durability.


2015 ◽  
Vol 1 (1) ◽  
pp. e1400129 ◽  
Author(s):  
Jianglan Shui ◽  
Min Wang ◽  
Feng Du ◽  
Liming Dai

The availability of low-cost, efficient, and durable catalysts for oxygen reduction reaction (ORR) is a prerequisite for commercialization of the fuel cell technology. Along with intensive research efforts of more than half a century in developing nonprecious metal catalysts (NPMCs) to replace the expensive and scarce platinum-based catalysts, a new class of carbon-based, low-cost, metal-free ORR catalysts was demonstrated to show superior ORR performance to commercial platinum catalysts, particularly in alkaline electrolytes. However, their large-scale practical application in more popular acidic polymer electrolyte membrane (PEM) fuel cells remained elusive because they are often found to be less effective in acidic electrolytes, and no attempt has been made for a single PEM cell test. We demonstrated that rationally designed, metal-free, nitrogen-doped carbon nanotubes and their graphene composites exhibited significantly better long-term operational stabilities and comparable gravimetric power densities with respect to the best NPMC in acidic PEM cells. This work represents a major breakthrough in removing the bottlenecks to translate low-cost, metal-free, carbon-based ORR catalysts to commercial reality, and opens avenues for clean energy generation from affordable and durable fuel cells.


2018 ◽  
Vol 6 (12) ◽  
pp. 16032-16038 ◽  
Author(s):  
Guangyuan Ren ◽  
Yunan Li ◽  
Quanshui Chen ◽  
Yong Qian ◽  
Jugong Zheng ◽  
...  

Nanoscale ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 2423-2433 ◽  
Author(s):  
Hyunsu Han ◽  
Yuseong Noh ◽  
Yoongon Kim ◽  
Won Suk Jung ◽  
Seongmin Park ◽  
...  

A highly efficient multidirectional N-doped porous carbon network with plenty of graphitic N-species has been explored as cathode catalysts in fuel cells.


2020 ◽  
Vol 31 (12) ◽  
pp. 125404 ◽  
Author(s):  
Siyu Wang ◽  
Lulu Chen ◽  
Xiangjian Liu ◽  
Ling Long ◽  
Haohui Liu ◽  
...  

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