Decorated traditional cellulose with nanoscale chiral metal-organic frameworks for enhanced enantioselective capture

2021 ◽  
Author(s):  
Yun Guo ◽  
Ling Zhang ◽  
Kexuan Wang ◽  
Ajuan Yu ◽  
Shusheng Zhang ◽  
...  

Herein, a rapid approach toward the size/morphology-controlled synthesis of [Cu(L-mal)(bipy)·2H2O] (CuLBH) was developed by adjusting the concentration of 2-methylimidazole (2-MI) and copper ions. The chiral separation efficiency test indicated that...

CrystEngComm ◽  
2021 ◽  
Author(s):  
Qing Luo ◽  
Zhen Ding ◽  
Huamin Sun ◽  
Zhen Cheng ◽  
Naien SHI ◽  
...  

Ultrathin two-dimensional (2D) metal-organic framework (MOF) nanosheets are prosperous advanced materials due to their particularly thin thickness and exposed active sites. The difficulty in the controlled synthesis of 2D MOF...


JACS Au ◽  
2021 ◽  
Author(s):  
Young Hun Lee ◽  
YongSung Kwon ◽  
Chaehoon Kim ◽  
Young-Eun Hwang ◽  
Minkee Choi ◽  
...  

RSC Advances ◽  
2021 ◽  
Vol 11 (18) ◽  
pp. 10540-10547
Author(s):  
Anxia Li ◽  
Xiaoxin Yang ◽  
Juan Chen

In this study, we reported a new approach for the size-controlled synthesis of uniform iron(iii)-based MIL-53 nanocrystals using the non-ionic surfactant PVP. A combinational therapeutic approach was presented for drug delivery and ROS therapy.


The Analyst ◽  
2020 ◽  
Vol 145 (22) ◽  
pp. 7349-7356 ◽  
Author(s):  
Kui Ren ◽  
Xiao-Feng Guo ◽  
Ying-Jie Tang ◽  
Bo-Hui Huang ◽  
Hong Wang

Fluorescent sensing experiments were carried out to compare the sensing performance for folic acid between bulk and nano Tb-MOFs.


2021 ◽  
Author(s):  
Qi Xue ◽  
Bryan Kit Yue Ng ◽  
Ho-wing Man ◽  
Tai-Sing Wu ◽  
Yun-Liang Soo ◽  
...  

Precisely tuning the nuclearity of supported metal nanoclusters is pivotal for designing more superior catalytic systems, but it remains practically challenging. By utilising the chemical and molecular specificity of UiO-66-NH2...


Small ◽  
2016 ◽  
Vol 12 (17) ◽  
pp. 2365-2375 ◽  
Author(s):  
Shuhai Wang ◽  
Minqi Chen ◽  
Yanyu Xie ◽  
Yanan Fan ◽  
Dawei Wang ◽  
...  

2018 ◽  
Vol 10 (44) ◽  
pp. 38051-38056 ◽  
Author(s):  
Jiayi Liu ◽  
Xuning Li ◽  
Biao Liu ◽  
Chunxiao Zhao ◽  
Zhichong Kuang ◽  
...  

Molecules ◽  
2021 ◽  
Vol 26 (12) ◽  
pp. 3481
Author(s):  
Marc Wagemann ◽  
Natalia Radzik ◽  
Artur Krzyżak ◽  
Alina Adams

Metal–organic frameworks (MOFs) have great potential as an efficient alternative to current separation and purification procedures of a large variety of solvent mixtures—a critical process in many applications. Due to the huge number of existing MOFs, it is of key importance to identify high-throughput analytical tools, which can be used for their screening and performance ranking. In this context, the present work introduces a simple, fast, and inexpensive approach by compact low-field proton nuclear magnetic resonance (NMR) relaxometry to investigate the efficiency of MOF materials for the separation of a binary solvent mixture. The mass proportions of two solvents within a particular solvent mixture can be quantified before and after separation with the help of a priori established correlation curves relating the effective transverse relaxation times T2eff and the mass proportions of the two solvents. The new method is applied to test the separation efficiency of powdered UiO-66(Zr) for various solvent mixtures, including linear and cyclic alkanes and benzene derivate, under static conditions at room temperature. Its reliability is demonstrated by comparison with results from 1H liquid-state NMR spectroscopy.


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