Reaction Mechanisms of Cylco[18]carbon and Triplet Oxygen

Author(s):  
Jialu Chen ◽  
Liang Sun ◽  
Rui Qin Zhang

Recently, a new carbon allotrope, cyclo[18]carbon molecule of alternating short and long carbon-carbon bonds has been synthesized and characterized in the condensed phase. Inspired by experiments, a lot of theoretical...

2017 ◽  
Vol 15 (10) ◽  
pp. 2163-2167 ◽  
Author(s):  
Zhouting Rong ◽  
Antonio M. Echavarren

The polycyclisation of polyeneynes catalyzed by gold(i) has been extended for the first time to the simultaneous formation of up to four carbon–carbon bonds, leading to steroid-like molecules with high stereoselectivity in a single step with low catalyst loadings.


ChemInform ◽  
2010 ◽  
Vol 28 (4) ◽  
pp. no-no
Author(s):  
S. F. SELLERS

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