scholarly journals Coordination sphere hydrogen bonding as a structural element in metal–organic Frameworks

2021 ◽  
Author(s):  
Chris S. Hawes
Keyword(s):  
Hydrogen Bonding ◽  
Coordination Sphere ◽  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Ligand Design ◽  
Design Strategies ◽  
Structural Element ◽  
Metal Organic

Coordination sphere hydrogen bonding in coordination polymers and metal–organic frameworks (MOFs) is examined as a structurally and chemically stabilising influence, accessible through ligand design strategies.

Piecewise 3D Printing of Crystallographic Data for Post-Printing Construction

2019 ◽  
Author(s):  
Matthew Brown ◽  
David Hartling ◽  
Hamel N. Tailor ◽  
Ken Van Wieren ◽  
Gary Houghton ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
3D Printing ◽  
Small Molecules ◽  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Crystallographic Data ◽  
Metal Organic ◽  
Hydrogen Bonding Networks ◽  
Time Reduction ◽  
Size Limits

A method of 3D printing complex or challenging structures by breaking them into parts with connectors, printing each part separately, and then assembling the structure post-printing has been developed. This has advantages such as multicoloured printing, framework optimization and reduction, print time reduction, and can be used to bypass print tray size limits. This method is particularly applicable to extended structures such as coordination polymers, metal-organic frameworks, and hydrogen bonding networks, but examples where it can be used to simplify the printing of small molecules are also shown.

scholarly journals Piecewise 3D Printing of Crystallographic Data for Post-Printing Construction

2019 ◽  
Author(s):  
Matthew Brown ◽  
David Hartling ◽  
Hamel N. Tailor ◽  
Ken Van Wieren ◽  
Gary Houghton ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
3D Printing ◽  
Small Molecules ◽  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Crystallographic Data ◽  
Metal Organic ◽  
Hydrogen Bonding Networks ◽  
Time Reduction ◽  
Size Limits

A method of 3D printing complex or challenging structures by breaking them into parts with connectors, printing each part separately, and then assembling the structure post-printing has been developed. This has advantages such as multicoloured printing, framework optimization and reduction, print time reduction, and can be used to bypass print tray size limits. This method is particularly applicable to extended structures such as coordination polymers, metal-organic frameworks, and hydrogen bonding networks, but examples where it can be used to simplify the printing of small molecules are also shown.

Piecewise 3D Printing of Crystallographic Data for Post-Printing Construction

2019 ◽  
Author(s):  
Matthew Brown ◽  
David Hartling ◽  
Hamel N. Tailor ◽  
Ken Van Wieren ◽  
Gary Houghton ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
3D Printing ◽  
Small Molecules ◽  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Crystallographic Data ◽  
Metal Organic ◽  
Hydrogen Bonding Networks ◽  
Time Reduction ◽  
Size Limits

A method of 3D printing complex or challenging structures by breaking them into parts with connectors, printing each part separately, and then assembling the structure post-printing has been developed. This has advantages such as multicoloured printing, framework optimization and reduction, print time reduction, and can be used to bypass print tray size limits. This method is particularly applicable to extended structures such as coordination polymers, metal-organic frameworks, and hydrogen bonding networks, but examples where it can be used to simplify the printing of small molecules are also shown.

scholarly journals Synthesis of Atomically Precise Single-Crystalline Ru2-Based Coordination Polymers

2020 ◽  
Author(s):  
Wen-Yang Gao ◽  
Gerard Van Trieste ◽  
David Powers
Keyword(s):  
Heterogeneous Catalyst ◽  
Coordination Sphere ◽  
Coordination Polymers ◽  
Network Topology ◽  
Metal Organic Frameworks ◽  
Systematic Variation ◽  
Single Crystalline ◽  
Metal Organic ◽  
Crystalline Metal

Methods to incorporate kinetically inert metal nodes and highly basic ligands into single-crystalline metal-organic frameworks (MOFs) are scarce, which prevents synthesis and systematic variation of many potential heterogeneous catalyst materials. Here we demonstrate that metallopolymerization of kinetically inert Ru<sub>2</sub> metallomonomers via labile Ag–N bonds provides access to a family of atomically precise single-crystalline Ru<sub>2</sub>-based coordination polymers with varied network topology and primary coordination sphere.

scholarly journals Piecewise 3D Printing of Crystallographic Data for Post-Printing Construction

2019 ◽  
Author(s):  
Matthew Brown ◽  
David Hartling ◽  
Hamel N. Tailor ◽  
Ken Van Wieren ◽  
Gary Houghton ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
3D Printing ◽  
Small Molecules ◽  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Crystallographic Data ◽  
Metal Organic ◽  
Hydrogen Bonding Networks ◽  
Time Reduction ◽  
Size Limits

A method of 3D printing complex or challenging structures by breaking them into parts with connectors, printing each part separately, and then assembling the structure post-printing has been developed. This has advantages such as multicoloured printing, framework optimization and reduction, print time reduction, and can be used to bypass print tray size limits. This method is particularly applicable to extended structures such as coordination polymers, metal-organic frameworks, and hydrogen bonding networks, but examples where it can be used to simplify the printing of small molecules are also shown.

scholarly journals Piecewise 3D Printing of Crystallographic Data for Post-Printing Construction

2019 ◽  
Author(s):  
Matthew Brown ◽  
David Hartling ◽  
Hamel N. Tailor ◽  
Ken Van Wieren ◽  
Gary Houghton ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
3D Printing ◽  
Small Molecules ◽  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Crystallographic Data ◽  
Metal Organic ◽  
Hydrogen Bonding Networks ◽  
Time Reduction ◽  
Size Limits

A method of 3D printing complex or challenging structures by breaking them into parts with connectors, printing each part separately, and then assembling the structure post-printing has been developed. This has advantages such as multicoloured printing, framework optimization and reduction, print time reduction, and can be used to bypass print tray size limits. This method is particularly applicable to extended structures such as coordination polymers, metal-organic frameworks, and hydrogen bonding networks, but examples where it can be used to simplify the printing of small molecules are also shown.

Piecewise 3D Printing of Crystallographic Data for Post-Printing Construction

2019 ◽  
Author(s):  
Matthew Brown ◽  
David Hartling ◽  
Hamel N. Tailor ◽  
Ken Van Wieren ◽  
Gary Houghton ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
3D Printing ◽  
Small Molecules ◽  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Crystallographic Data ◽  
Metal Organic ◽  
Hydrogen Bonding Networks ◽  
Time Reduction ◽  
Size Limits

A method of 3D printing complex or challenging structures by breaking them into parts with connectors, printing each part separately, and then assembling the structure post-printing has been developed. This has advantages such as multicoloured printing, framework optimization and reduction, print time reduction, and can be used to bypass print tray size limits. This method is particularly applicable to extended structures such as coordination polymers, metal-organic frameworks, and hydrogen bonding networks, but examples where it can be used to simplify the printing of small molecules are also shown.

scholarly journals Piecewise 3D Printing of Crystallographic Data for Post-Printing Construction

2019 ◽  
Author(s):  
Matthew Brown ◽  
David Hartling ◽  
Hamel N. Tailor ◽  
Ken Van Wieren ◽  
Gary Houghton ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
3D Printing ◽  
Small Molecules ◽  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Crystallographic Data ◽  
Metal Organic ◽  
Hydrogen Bonding Networks ◽  
Time Reduction ◽  
Size Limits

A method of 3D printing complex or challenging structures by breaking them into parts with connectors, printing each part separately, and then assembling the structure post-printing has been developed. This has advantages such as multicoloured printing, framework optimization and reduction, print time reduction, and can be used to bypass print tray size limits. This method is particularly applicable to extended structures such as coordination polymers, metal-organic frameworks, and hydrogen bonding networks, but examples where it can be used to simplify the printing of small molecules are also shown.

scholarly journals Piecewise 3D Printing of Crystallographic Data for Post-Printing Construction

2019 ◽  
Author(s):  
Matthew Brown ◽  
David Hartling ◽  
Hamel N. Tailor ◽  
Ken Van Wieren ◽  
Gary Houghton ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
3D Printing ◽  
Small Molecules ◽  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Crystallographic Data ◽  
Metal Organic ◽  
Hydrogen Bonding Networks ◽  
Time Reduction ◽  
Size Limits

A method of 3D printing complex or challenging structures by breaking them into parts with connectors, printing each part separately, and then assembling the structure post-printing has been developed. This has advantages such as multicoloured printing, framework optimization and reduction, print time reduction, and can be used to bypass print tray size limits. This method is particularly applicable to extended structures such as coordination polymers, metal-organic frameworks, and hydrogen bonding networks, but examples where it can be used to simplify the printing of small molecules are also shown.

scholarly journals Synthesis of Atomically Precise Single-Crystalline Ru2-Based Coordination Polymers

2020 ◽  
Author(s):  
Wen-Yang Gao ◽  
Gerard Van Trieste ◽  
David Powers
Keyword(s):  
Heterogeneous Catalyst ◽  
Coordination Sphere ◽  
Coordination Polymers ◽  
Network Topology ◽  
Metal Organic Frameworks ◽  
Systematic Variation ◽  
Single Crystalline ◽  
Metal Organic ◽  
Crystalline Metal

Methods to incorporate kinetically inert metal nodes and highly basic ligands into single-crystalline metal-organic frameworks (MOFs) are scarce, which prevents synthesis and systematic variation of many potential heterogeneous catalyst materials. Here we demonstrate that metallopolymerization of kinetically inert Ru<sub>2</sub> metallomonomers via labile Ag–N bonds provides access to a family of atomically precise single-crystalline Ru<sub>2</sub>-based coordination polymers with varied network topology and primary coordination sphere.

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