scholarly journals Using geometric simulation software ‘GASP’ to model conformational flexibility in a family of zinc metal-organic frameworks

2021 ◽  
Author(s):  
William James Gee ◽  
Stephen A Wells ◽  
Simon Teat ◽  
Paul R Raithby ◽  
Andrew D Burrows
Keyword(s):  
Metal Organic Frameworks ◽  
Conformational Flexibility ◽  
Tricarboxylic Acid ◽  
Simulation Software ◽  
Nitrate Hexahydrate ◽  
Zinc Metal ◽  
Acid Ligand ◽  
Metal Organic ◽  
Geometric Simulation

Here, a new tripodal tricarboxylic acid ligand, 4,4'-(4'-(4'-carboxy-[1,1'-biphenyl]-4-yl)-[2,2':6',2''-terpyridine]-5,5''-diyl)-dibenzoic acid (H3cbt), was synthesised using a three-step convergent strategy. Subsequent reactions with zinc(II) nitrate hexahydrate yielded three metal-organic frameworks (MOFs). The three...

Solvent-induced construction of two zinc metal–organic frameworks for highly selective detection of nitroaromatic explosives

CrystEngComm ◽  
2016 ◽  
Vol 18 (22) ◽  
pp. 4102-4108 ◽  
Author(s):  
Chuanqi Zhang ◽  
Yan Yan ◽  
Libo Sun ◽  
Zhiqiang Liang ◽  
Jiyang Li
Keyword(s):  
High Efficiency ◽  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Tricarboxylic Acid ◽  
Nitroaromatic Compounds ◽  
Selective Detection ◽  
Nitroaromatic Explosives ◽  
Zinc Metal ◽  
Metal Organic

Two three-dimensional metal–organic frameworks 1 and 2 based on p-terphenyl-3,4′′,5-tricarboxylic acid (H3TPT) were synthesized by controlling the solvent media. These two MOFs exhibit high efficiency for the recyclable detection of nitroaromatic compounds.

Lanthanide metal–organic frameworks based on a 1,2,3-triazole-containing tricarboxylic acid ligand for luminescence sensing of metal ions and nitroaromatic compounds

RSC Advances ◽  
2016 ◽  
Vol 6 (63) ◽  
pp. 57828-57834 ◽  
Author(s):  
Di Wang ◽  
Libo Sun ◽  
Chuanqing Hao ◽  
Yan Yan ◽  
Zhiqiang Liang
Keyword(s):  
Metal Ions ◽  
Metal Organic Frameworks ◽  
Tricarboxylic Acid ◽  
Nitroaromatic Compounds ◽  
Selective Detection ◽  
Acid Ligand ◽  
Metal Organic ◽  
Lanthanide Metal

A series of novel 3D lanthanide MOFs based on unsymmetrical 1,2,3-triazole-containing tricarboxylic acid ligand (H3TAIP) has been synthesized. Compound 1 [Tb(TAIP)(DMF)2] exhibits selective detection of 4-nitrotoluene and Fe3+ ion.

Phase selectivity and tunable photophysical nature of rare earth metal–organic frameworks of EuxY1−x-PTC (H3PTC = 2,4,6-pyridine tricarboxylic acid; x = 0–1)

2020 ◽  
Vol 49 (42) ◽  
pp. 14985-14994
Author(s):  
Xu-Sheng Gao ◽  
Mei-Juan Ding ◽  
Jin Zhang ◽  
Li-Duo Zhao ◽  
Xiao-Ming Ren
Keyword(s):  
Rare Earth ◽  
Solid Solutions ◽  
Rare Earth Metal ◽  
Metal Organic Frameworks ◽  
Earth Metal ◽  
Tricarboxylic Acid ◽  
Excitation Wavelength ◽  
Metal Organic ◽  
Phase Selectivity

All solid solutions (EuxY1−x-PTC, x = 0.013–0.82) are isomorphic to Eu-PTC, but different from Y-PTC, and show phase selectivity as well as excitation wavelength dependent emission.

Lanthanide metal–organic frameworks based on the 4,4′-oxybisbenzoic acid ligand: synthesis, structures and physical properties

2015 ◽  
Vol 39 (12) ◽  
pp. 9872-9878 ◽  
Author(s):  
Yun Li ◽  
Ning Wang ◽  
Yan-Ju Xiong ◽  
Qian Cheng ◽  
Jie-Fang Fang ◽  
...  
Keyword(s):  
Physical Properties ◽  
Solvothermal Synthesis ◽  
Metal Organic Frameworks ◽  
Lanthanide Ions ◽  
Acid Ligand ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Ligand Synthesis

Using solvothermal synthesis, eight new 3D microporous lanthanide-ions-based MOFs constructed from 4,4′-oxybisbenzoic acid were obtained and displayed two types of architecture.

scholarly journals Post-synthetic modification of zinc metal-organic frameworks through palladium-catalysed carbon–carbon bond formation

2015 ◽  
Vol 792 ◽  
pp. 134-138 ◽  
Author(s):  
Andrew D. Burrows ◽  
Laura C. Fisher ◽  
Timothy J. Mays ◽  
Sean P. Rigby ◽  
Sharon E. Ashbrook ◽  
...  
Keyword(s):  
Bond Formation ◽  
Metal Organic Frameworks ◽  
Carbon Bond ◽  
Zinc Metal ◽  
Carbon Carbon Bond ◽  
Metal Organic

Two new Zn2+/Cd2+ Metal-Organic Frameworks (MOFs) constructed from asymmetrical tricarboxylic acid ligands

2020 ◽  
Vol 1205 ◽  
pp. 127620 ◽  
Author(s):  
Yan-Ning Wang ◽  
Shao-Dan Wang ◽  
He Qi ◽  
Wen-Jing Wang ◽  
Xuan-Xuan Hao
Keyword(s):  
Metal Organic Frameworks ◽  
Tricarboxylic Acid ◽  
Metal Organic
Sign in / Sign up

Export Citation Format

Share Document