Sensitive and selective determination of trace amounts of mercury ions using dimercaprol functionalized graphene quantum dot modified glassy carbon electrode

Nanoscale ◽  
2021 ◽  
Author(s):  
Maria Esmaeili ◽  
Fatemeh Ahour ◽  
Sajjad Keshipour

A novel nanomaterial is synthesized based on the functionalization of graphene quantum dot with dimercaprol (GQD-DMC). Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and high-resolution transmission electron microscopy...

2016 ◽  
Vol 6 (4) ◽  
pp. 235-241 ◽  
Author(s):  
Nastaran Hashemzadeh ◽  
Mohammad Hasanzadeh ◽  
Nasrin Shadjou ◽  
Jamal Eivazi-Ziaei ◽  
Maryam Khoubnasabjafari ◽  
...  

2012 ◽  
Vol 531 ◽  
pp. 419-422 ◽  
Author(s):  
Zong Hua Wang ◽  
Shu Yan Yao ◽  
Jian Fei Xia ◽  
Fei Fei Zhang ◽  
Xin Mei Guo ◽  
...  

Abstract: Graphene/Carbon Nanotube hybrid films modified glassy carbon electrode (GN-CNT/GC) was fabricated as electrochemical sensor for the sensitive and rapid determination of rutin. The electrochemical behaviors of rutin at the GN-CNT/GC have been investigated. Rutin can generate a pair of well-defined redox peaks at the GN-CNT/GC located at 0.450 V (Epa) and 0.409 V (Epc). Compared with graphene modified glassy carbon electrode (GN/GC) and carbon nanotube modified glassy carbon electrode (CNT/GC), GN-CNT/GC showed a higher catalytic activity toward rutin. This result indicates that the GN-CNT hybrid films as a modifier strengthens the adsorption of rutin. Cyclic voltammetry (CV), different pulse voltammetry (DPV) and transmission electron microscopy (TEM) were employed to characterize the electrochemical sensor and hybrid films. Under the optimal conditions, the oxidation peak current is linear to the rutin concentration over the range of 2.0×10-7-6.0×10-5 M and the detection limits were 1.0×10-7 M.


ACS Nano ◽  
2012 ◽  
Vol 6 (10) ◽  
pp. 9021-9032 ◽  
Author(s):  
Doris Segets ◽  
J. Matthew Lucas ◽  
Robin N. Klupp Taylor ◽  
Marcus Scheele ◽  
Haimei Zheng ◽  
...  

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