scholarly journals Molecular design of efficient yellow- to red-emissive alkynylgold(iii) complexes for the realization of thermally activated delayed fluorescence (TADF) and their applications in solution-processed organic light-emitting devices

2021 ◽  
Author(s):  
Cathay Chai Au-Yeung ◽  
Lok-Kwan Li ◽  
Man-Chung Tang ◽  
Shiu-Lun Lai ◽  
Wai-Lung Cheung ◽  
...  

We report the design of a new class of fused heterocyclic alkynyl ligand-containing gold(iii) complexes, which shows tunable emission colors spanning yellow to red region and exhibits thermally activated delayed fluorescence (TADF) properties.

2021 ◽  
Author(s):  
Lok-Kwan Li ◽  
Wing-Kei Kwok ◽  
Man-Chung Tang ◽  
Wai-Lung Cheung ◽  
Shiu-Lun Lai ◽  
...  

A new class of carbazolylgold(iii) C^C^N dendrimers with thermally activated delayed fluorescence properties has been designed and synthesized for the realzaqtion of operationally stable solution-processed organic light-emitting devices.


Author(s):  
Zhou Fang ◽  
Shengyue Wang ◽  
Junxu Liao ◽  
Xinrui Chen ◽  
Yuanyuan Zhu ◽  
...  

Efficient blue thermally activated delayed fluorescence (TADF) emitter is still a challenge in solution-processed organic light-emitting diodes (OLEDs). In this contribution, two asymmetric molecules of TTT-Ac and TTT-2Ac were synthesized...


2018 ◽  
Vol 14 ◽  
pp. 282-308 ◽  
Author(s):  
Thanh-Tuân Bui ◽  
Fabrice Goubard ◽  
Malika Ibrahim-Ouali ◽  
Didier Gigmes ◽  
Frédéric Dumur

The design of highly emissive and stable blue emitters for organic light emitting diodes (OLEDs) is still a challenge, justifying the intense research activity of the scientific community in this field. Recently, a great deal of interest has been devoted to the elaboration of emitters exhibiting a thermally activated delayed fluorescence (TADF). By a specific molecular design consisting into a minimal overlap between the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) due to a spatial separation of the electron-donating and the electron-releasing parts, luminescent materials exhibiting small S1–T1 energy splitting could be obtained, enabling to thermally upconvert the electrons from the triplet to the singlet excited states by reverse intersystem crossing (RISC). By harvesting both singlet and triplet excitons for light emission, OLEDs competing and sometimes overcoming the performance of phosphorescence-based OLEDs could be fabricated, justifying the interest for this new family of materials massively popularized by Chihaya Adachi since 2012. In this review, we proposed to focus on the recent advances in the molecular design of blue TADF emitters for OLEDs during the last few years.


2020 ◽  
Vol 1 (8) ◽  
pp. 2862-2871
Author(s):  
Fabian Hundemer ◽  
Ettore Crovini ◽  
Yoshimasa Wada ◽  
Hironori Kaji ◽  
Stefan Bräse ◽  
...  

We report a new emitter 3,4,5-3TCz-TTT based on a tris(triazolo)triazine acceptor that shows thermally activated delayed fluorescence and cross-compare its performance with the recently reported analogue, 3DMAC-TTT.


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