scholarly journals The mechanism of oxidative addition of Pd(0) to Si–H bonds: electronic effects, reaction mechanism, and hydrosilylation

2021 ◽  
Author(s):  
Michael R. Hurst ◽  
Lev N. Zakharov ◽  
Amanda K. Cook
Keyword(s):  
Reaction Mechanism ◽  
Addition Reaction ◽  
Oxidative Addition ◽  
Mechanistic Studies ◽  
Electronic Effects ◽  
Rate Law ◽  
Oxidative Addition Reaction

Mechanistic studies reveal the rate law, an H/D KIE, and that the silane’s electronics impact the thermodynamic and kinetic energetics of the oxidative addition reaction. These electronic effects are relevant in the hydrosilylation of alkynes.

ChemInform Abstract: Oxidative Addition Reaction of Unsaturated Acid Esters with 1,3- Dimethyluracil and Pyrimidine Nucleosides.

ChemInform ◽  
2010 ◽  
Vol 25 (18) ◽  
pp. no-no
Author(s):  
G. A. TOLSTIKOV ◽  
A. G. MUSTAFIN ◽  
R. R. GATAULLIN ◽  
L. V. SPIRIKHIN ◽  
V. S. SULTANOVA ◽  
...  
Keyword(s):  
Unsaturated Acid ◽  
Addition Reaction ◽  
Oxidative Addition ◽  
Pyrimidine Nucleosides ◽  
Oxidative Addition Reaction ◽  
Acid Esters

Insights into the Halogen Oxidative Addition Reaction to Dinuclear Gold(I) Di(NHC) Complexes

2016 ◽  
Vol 22 (29) ◽  
pp. 10211-10224 ◽  
Author(s):  
Marco Baron ◽  
Cristina Tubaro ◽  
Marino Basato ◽  
Abdirisak Ahmed Isse ◽  
Armando Gennaro ◽  
...  
Keyword(s):  
Addition Reaction ◽  
Oxidative Addition ◽  
Oxidative Addition Reaction

Preparation of a monomeric aluminium–diazabutadiene complex via an oxidative addition reaction

1998 ◽  
pp. 1937-1938 ◽  
Author(s):  
Alan H. Cowley ◽  
John D. Gorden ◽  
Colin D. Abernethy ◽  
Jason A. C. Clyburne ◽  
Brian G. McBurnett
Keyword(s):  
Addition Reaction ◽  
Oxidative Addition ◽  
Oxidative Addition Reaction
Sign in / Sign up

Export Citation Format

Share Document