Stabilization of lithium metal anodes by conductive metal–organic framework architectures

Author(s):  
Jing Zhao ◽  
Hongye Yuan ◽  
Guiling Wang ◽  
Xiao Feng Lim ◽  
Hualin Ye ◽  
...  

The Cu-foil current collectors with Ni3(HITP)2 films were prepared to reduce the energy barrier of the current collector surface and thus provide a uniform seeding layer for the subsequent deposition of Li in Li-ion batteries.

2020 ◽  
Vol 8 (3) ◽  
pp. 1425-1431 ◽  
Author(s):  
Dongming Yin ◽  
Gang Huang ◽  
Shaohua Wang ◽  
Dongxia Yuan ◽  
Xuxu Wang ◽  
...  

A free-standing and integrated 3D nitrogen–carbon co-doped Cu nanorod arrays (3D NC/Cu) as a completely new current collector is in situ derived from the metal–organic framework (MOF) and can effectively address dendrite issues for lithium batteries.


2016 ◽  
Vol 52 (14) ◽  
pp. 3003-3006 ◽  
Author(s):  
Linyi Bai ◽  
Binbin Tu ◽  
Yi Qi ◽  
Qiang Gao ◽  
Dong Liu ◽  
...  

Incorporating supramolecular recognition units, crown ether rings, into metal–organic frameworks enables the docking of metal ions through complexation for enhanced performance.


2017 ◽  
Vol 8 (6) ◽  
pp. 4285-4291 ◽  
Author(s):  
Wen Liu ◽  
Yingying Mi ◽  
Zhe Weng ◽  
Yiren Zhong ◽  
Zishan Wu ◽  
...  

Stable-cycling Li metal anode is realized with a MOF layer regulating Li-ion transport and Li deposition via chemical interactions.


2020 ◽  
Vol 11 (29) ◽  
pp. 7665-7671 ◽  
Author(s):  
Zhiyong Wang ◽  
Gang Wang ◽  
Haoyuan Qi ◽  
Mao Wang ◽  
Mingchao Wang ◽  
...  

Ultrathin and large-sized 2D conjugated MOF single-crystalline nanosheets are synthesized, which allow fast ion diffusion and high utilization of active sites, and therefore exhibit remarkable performance for Li-ion batteries.


2017 ◽  
Vol 43 (16) ◽  
pp. 13224-13232 ◽  
Author(s):  
Vaiyapuri Soundharrajan ◽  
Balaji Sambandam ◽  
Jinju Song ◽  
Sungjin Kim ◽  
Jeonggeun Jo ◽  
...  

2019 ◽  
Vol 236 ◽  
pp. 73-76 ◽  
Author(s):  
Marine Cognet ◽  
Thibaut Gutel ◽  
Romain Gautier ◽  
Xavier F. Le Goff ◽  
Adel Mesbah ◽  
...  

2021 ◽  
Vol 6 (2) ◽  
pp. 22
Author(s):  
Fatemeh Keshavarz ◽  
Marius Kadek ◽  
Bernardo Barbiellini ◽  
Arun Bansil

We discuss the characteristic factors that determine the electrochemical potentials in a metal-organic framework used as cathode for Li-ion batteries via density functional theory-based simulations. Our focus is on MIL-101(Fe) cathode material. Our study gives insight into the role of local atomic environment and structural deformations in generating electrochemical potential.


2015 ◽  
Vol 161 ◽  
pp. 712-715 ◽  
Author(s):  
Yan Zhang ◽  
Yu-Bin Niu ◽  
Ting Liu ◽  
Yu-Tao Li ◽  
Min-Qiang Wang ◽  
...  

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