Enhancing proton conductivity in Zr-MOFs through tuning metal cluster connectivity

High Proton ◽

Metal Organic

We design and synthesize two stable Zr(IV)-based metal-organic frameworks with high proton conductivity, namely BUT-76 and BUT-77, which are constructed with the same sulfonic acid containing ligand and 8/12 connected...

Metal–organic frameworks derived from a semi-rigid anthracene-based ligand and sulfonates: proton conductivity and dye degradation studies

CrystEngComm ◽

10.1039/d0ce01275k ◽

2021 ◽

Author(s):

Aurobinda Mohanty ◽

Udai P. Singh ◽

Arijit Ghorai ◽

Susanta Banerjee ◽

R. J. Butcher

Keyword(s):

Methylene Blue ◽

Relative Humidity ◽

Proton Conductivity ◽

Dye Degradation ◽

Methylene Blue Degradation ◽

High Proton ◽

Metal Organic ◽

Degradation Studies

The MOFs were constructed by ligand AHP and sulfonate analogues. MOF4 exhibits a high proton conductivity of 1.95 × 10−3 S cm−1 at 95 °C and 98% relative humidity. MOFs 1–5 also serve as photocatalysts for methylene blue degradation.

High proton conductivity in cyanide-bridged metal–organic frameworks: understanding the role of water

Journal of Materials Chemistry A ◽

10.1039/c5ta05280g ◽

2015 ◽

Vol 3 (44) ◽

pp. 22347-22352 ◽

Cited By ~ 36

Author(s):

Yuan Gao ◽

Richard Broersen ◽

Wouter Hageman ◽

Ning Yan ◽

Marjo C. Mittelmeijer-Hazeleger ◽

...

Keyword(s):

Proton Conductivity ◽

Water Molecules ◽

Lattice Water ◽

High Proton ◽

Metal Organic

Hop hop hop: the proton conductivity of the [Nd(mpca)2Nd(H2O)6Mo(CN)8]·nH2O is enabled by lattice water molecules in its channels.

Trojan Horse Thiocyanate: Induction and Control of High Proton Conductivity in CPO-27/MOF-74 Metal–Organic Frameworks by Metal Selection and Solvent-Free Mechanochemical Dosing

ACS Applied Materials & Interfaces ◽

10.1021/acsami.1c06346 ◽

2021 ◽

Author(s):

Magdalena Lupa ◽

Paweł Kozyra ◽

Gabriela Jajko ◽

Dariusz Matoga

Keyword(s):

Proton Conductivity ◽

Trojan Horse ◽

Solvent Free ◽

High Proton ◽

Metal Organic ◽

And Control

Ba-MOFs with tetrazole-based acetic acids: unusual configuration, novel topology and high proton conductivity

Dalton Transactions ◽

10.1039/d1dt02116h ◽

2021 ◽

Author(s):

Jie Yang ◽

Shunlin Zhang ◽

Zhe Feng ◽

Ying Cao ◽

Dunru Zhu

Keyword(s):

Proton Conductivity ◽

Proton Exchange Membrane ◽

Proton Exchange ◽

Conductive Materials ◽

High Proton ◽

Metal Organic ◽

Exchange Membrane ◽

Acetic Acids

Metal-organic frameworks (MOFs) as proton conductive materials have attracted increasing attention due to their applications in proton-exchange membrane fuel cells. While the majority of the MOFs are based on transition...

Synthesis and properties poly(arylene ether sulfone)s with pendant hyper-sulfonic acid

RSC Advances ◽

10.1039/c5ra02107c ◽

2015 ◽

Vol 5 (48) ◽

pp. 38298-38307 ◽

Cited By ~ 7

Author(s):

Jinhui Pang ◽

Sinan Feng ◽

Haibo Zhang ◽

Zhenhua Jiang ◽

Guibin Wang

Keyword(s):

Proton Conductivity ◽

Dimensional Stability ◽

Sulfonic Acid ◽

Side Chains ◽

Arylene Ether ◽

High Proton ◽

Sulfonic Acid Groups ◽

Aromatic Side Chains

A novel poly(arylene ether sulfone)s with pendant multiple sulfonic acid groups on aromatic side chains was prepared by graft method, they displayed high proton conductivity and good dimensional stability.