Liquid hydrogen sulphide as an ionising solvent. Part I. Base analogues and their neutralisation with hydrogen halides

1966 ◽  
pp. 785 ◽  
Author(s):  
J. D. Cotton ◽  
T. C. Waddington
Keyword(s):  
Hydrogen Sulphide ◽  
Liquid Hydrogen ◽  
Hydrogen Halides

Some thermodynamic properties of liquid hydrogen sulphide and deuterium sulphide

1987 ◽  
Vol 19 (7) ◽  
pp. 703-710 ◽  
Author(s):  
A.G Cubitt ◽  
C Henderson ◽  
L.A.K Staveley ◽  
I.M.A Fonseca ◽  
A.G.M Ferreira ◽  
...  
Keyword(s):  
Thermodynamic Properties ◽  
Hydrogen Sulphide ◽  
Liquid Hydrogen

The Development of Low-Sour Gas Reserves Utilizing Direct-Injection Liquid Hydrogen Sulphide Scavengers

2001 ◽  
Author(s):  
J.G.R. Eylander ◽  
H.A. Holtman ◽  
T. Salma ◽  
M. Yuan ◽  
M. Callaway ◽  
...  
Keyword(s):  
Hydrogen Sulphide ◽  
Direct Injection ◽  
Liquid Hydrogen ◽  
Sour Gas

Hydrogen sulphide – halogen complexes studied by matrix isolation vibrational spectroscopy

1985 ◽  
Vol 63 (7) ◽  
pp. 1705-1707 ◽  
Author(s):  
U. P. Agarwal ◽  
A. J. Barnes ◽  
W. J. Orville-Thomas
Keyword(s):  
Low Temperature ◽  
Vibrational Spectroscopy ◽  
Infrared Spectra ◽  
Hydrogen Sulphide ◽  
Matrix Isolation ◽  
Reaction Products ◽  
Hydrogen Halides ◽  
Stretching Vibration

Infrared spectra are reported of mixtures of hydrogen sulphide with chlorine or bromine in low-temperature argon or nitrogen matrices. The H2S … Cl2 and H2S … Br2 complexes were identified from the perturbed halogen stretching vibration. Absorptions due to the corresponding hydrogen halides provided evidence that reaction was occurring between the hydrogen sulphide and halogen (despite the use of a twin-jet deposition), and other reaction products were tentatively identified from the observed absorptions.

The reaction of trimethylamine in liquid hydrogen sulphide: an electrical conductivity study

1983 ◽  
Vol 61 (6) ◽  
pp. 1142-1145 ◽  
Author(s):  
James D. Halliday ◽  
Patrick E. Bindner
Keyword(s):  
Electrical Conductivity ◽  
Dielectric Constant ◽  
Hydrogen Sulphide ◽  
Liquid Hydrogen ◽  
Weak Electrolyte ◽  
Temperature Range ◽  
Conductance Data ◽  
Brønsted Base ◽  
Electrical Conductivity Study ◽  
Hydrogen Bonded

The electrical conductivity of trimethylamine solutions (2.26 × 10−4 to 2.89 × 10−1 mol L−1) in liquid hydrogen sulphide over the temperature range −72.5 °C to +25.0 °C has been measured. The data indicate that the trimethylamine behaves as a Brønsted base in liquid hydrogen sulphide [1] and is protonated to form trimethylammonium hydrogensulphide. The latter[Formula: see text]behaves as a normal weak electrolyte in a solvent of low to medium dielectric constant [Formula: see text]. The conductance data as a function of temperature also show that trimethylamine exists both as a hydrogen bonded complex with H2S and as an unassociated molecule in liquid H2S.

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