Transition-metal complexes containing phosphorus ligands. Part V. Synthesis and reactivity of some iridium triaryl phosphite complexes: metal-assisted cleavage of ortho-carbon–hydrogen bonds in co-ordinated triaryl phosphite ligands

1971 ◽  
Vol 0 (0) ◽  
pp. 3413-3424 ◽  
Author(s):  
E. W. Ainscough ◽  
S. D. Robinson ◽  
J. J. Levison
Keyword(s):  
Transition Metal ◽  
Hydrogen Bonds ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Phosphorus Ligands ◽  
Carbon Hydrogen Bonds ◽  
Phosphite Ligands

Aerobic oxygenation catalyzed by first row transition metal complexes coordinated by tetradentate mono-carbon bridged bis-phenanthroline ligands: intra- versus intermolecular carbon–hydrogen bond activation

2019 ◽  
Vol 48 (19) ◽  
pp. 6396-6407 ◽  
Author(s):  
Kaiji Shen ◽  
Yael Diskin-Posner ◽  
Linda J. W. Shimon ◽  
Gregory Leitus ◽  
Raanan Carmieli ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Transition Metal ◽  
Hydrogen Bonds ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Bond Activation ◽  
Carbon Hydrogen Bond Activation ◽  
Carbon Hydrogen Bonds ◽  
Phenanthroline Ligands

Intra- and intermolecular aerobic oxygenation is initiated by activation of carbon–hydrogen bonds and/or O2 and propagated by an autoxidation pathway.

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