556. Kinetic studies of the oxidation of vanadium(III) by iron(III) in solution in aqueous perchloric acid

Journal of the Chemical Society (Resumed) ◽

10.1039/jr9620002841 ◽

1962 ◽

pp. 2841 ◽

Author(s):

W. C. E. Higginson ◽

A. G. Sykes

Keyword(s):

Perchloric Acid ◽

Kinetic Studies ◽

Aqueous Perchloric Acid

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Reactions of µ-hydroxo-dicobalt(III) complexes. Part IX. Equilibrium and kinetic studies of the reaction of the µ-amido-µ-hydroxo-bis[tetra-amminecobalt(III)] complex with selenate ions in aqueous perchloric acid solutions, and characterisation of the µ-amido-µ-selenato-bis[tetra-amminecobalt(III)] complex

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9730000504 ◽

1973 ◽

pp. 504-511 ◽

Author(s):

Siew-Wan Foong ◽

A. Geoffrey Sykes

Keyword(s):

Perchloric Acid ◽

Kinetic Studies ◽

Acid Solutions ◽

Aqueous Perchloric Acid

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Kinetic Studies of the Acid Hydrolysis of Aquaoxo[N-(2-pyridylmethyl)iminodiacetato]vanadium(IV) and Aqua(nitrilotriacetato)oxovanadate(IV) in Aqueous Perchloric Acid Solution

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.53.664 ◽

1980 ◽

Vol 53 (3) ◽

pp. 664-667 ◽

Author(s):

Masato Nishizawa ◽

Kazuo Saito

Keyword(s):

Acid Solution ◽

Acid Hydrolysis ◽

Perchloric Acid ◽

Kinetic Studies ◽

Perchloric Acid Solution ◽

Aqueous Perchloric Acid ◽

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Reactions of µ-hydroxo-dicobalt complexes. Part V. Equilibrium and kinetic studies on the reaction of the µ-amido-µ-hydroxo-bis[tetra-amminecobalt(III)] complex with sulphate in aqueous perchloric acid solutions

Journal of the Chemical Society A Inorganic Physical Theoretical ◽

10.1039/j19700003214 ◽

1970 ◽

Vol 0 (0) ◽

pp. 3214-3220 ◽

Author(s):

M. B. Stevenson ◽

A. G. Sykes ◽

R. S. Taylor

Keyword(s):

Perchloric Acid ◽

Kinetic Studies ◽

Acid Solutions ◽

Aqueous Perchloric Acid

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Reactions of µ-hydroxo-dicobalt(III) complexes. Part XII. Equilibrium and kinetic studies on hydroxo-bridge cleavage reactions of two triply-bridged dicobalt(III) complexes in aqueous perchloric acid solutions

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9740002198 ◽

1974 ◽

pp. 2198-2204 ◽

Author(s):

Julian D. Edwards ◽

Karl Wieghardt ◽

A. Geoffrey Sykes

Keyword(s):

Perchloric Acid ◽

Kinetic Studies ◽

Acid Solutions ◽

Aqueous Perchloric Acid ◽

Cleavage Reactions

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Reactions of µ-hydroxo-dicobalt(III) complexes. Part X. Kinetic studies of the reaction of the µ-amido-µ-hydroxo-bis[tetra-amminecobalt(III)] complex with phosphate ions in aqueous perchloric acid solutions and the characterisation of the µ-amido-µ-phosphato-bis[tetra-amminecobalt(III)] complex

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9730000829 ◽

1973 ◽

pp. 829-838 ◽

Author(s):

Julian D. Edwards ◽

Siew-Wan Foong ◽

A. Geoffrey Sykes

Keyword(s):

Perchloric Acid ◽

Kinetic Studies ◽

Acid Solutions ◽

Phosphate Ions ◽

Aqueous Perchloric Acid

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Amine oxidation. Part 16. Kinetic studies on the oxidation of some aminoalcohols by vanadium(V) ions in aqueous perchloric acid

Journal of the Chemical Society Perkin Transactions 2 ◽

10.1039/p29850000319 ◽

1985 ◽

pp. 319 ◽

Author(s):

Richard J. Hutchinson ◽

John R. Lindsay Smith ◽

Martyn V. Twigg

Keyword(s):

Perchloric Acid ◽

Kinetic Studies ◽

Amine Oxidation ◽

Aqueous Perchloric Acid

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ChemInform Abstract: Amine Oxidation. Part 16. Kinetic Studies on the Oxidation of Some Aminoalcohols by Vanadium(V) Ions in Aqueous Perchloric Acid.

Chemischer Informationsdienst ◽

10.1002/chin.198524115 ◽

1985 ◽

Vol 16 (24) ◽

Author(s):

R. J. HUTCHINSON ◽

J. R. L. SMITH ◽

M. V. TWIGG

Keyword(s):

Perchloric Acid ◽

Kinetic Studies ◽

Amine Oxidation ◽

Aqueous Perchloric Acid

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6. Kinetic studies of the oxidation of metal ions by cobalt(III) in solution in aqueous perchloric acid

Journal of the Chemical Society (Resumed) ◽

10.1039/jr9600000031 ◽

1960 ◽

pp. 31 ◽

Author(s):

D. R. Rosseinsky ◽

W. C. E. Higginson

Keyword(s):

Perchloric Acid ◽

Kinetic Studies ◽

Aqueous Perchloric Acid

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ChemInform Abstract: REACTIONS OF MU-HYDROXO-DICOBALT(III) COMPLEXES PART 12, EQUILIBRIUM AND KINETIC STUDIES ON HYDROXO-BRIDGE CLEAVAGE REACTIONS OF TWO TRIPLY-BRIDGED DICOBALT(III) COMPLEXES IN AQUEOUS PERCHLORIC ACID SOLUTIONS

Chemischer Informationsdienst ◽

10.1002/chin.197501033 ◽

1975 ◽

Vol 6 (1) ◽

pp. no-no

Author(s):

JULIAN D. EDWARDS ◽

KARL WIEGHARDT ◽

A. GEOFFREY SYKES

Keyword(s):

Perchloric Acid ◽

Kinetic Studies ◽

Acid Solutions ◽

Aqueous Perchloric Acid ◽

Cleavage Reactions

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Kinetic studies on the effect of acidity and temperature on the loss of optical activity of some butanediols

Australian Journal of Chemistry ◽

10.1071/ch9840767 ◽

1984 ◽

Vol 37 (4) ◽

pp. 767 ◽

Author(s):

KP Herlihy

Keyword(s):

Kinetic Parameters ◽

Optical Activity ◽

Perchloric Acid ◽

Activation Parameters ◽

Kinetic Studies ◽

Hydroxyl Group ◽

Aqueous Perchloric Acid

In aqueous perchloric acid, butane-1,2-diol (1) and butane-2,3-diol (2) give carbonyls and butane-1,3-diol (3) gives alkenols. The rate of loss of optical activity has been determined for these diols and butan-2-ol (4) over a range of temperatures and acidities. In 1 M acid at 100�C, the rates for (1), (2), (3) and (4) are in the ratio of 1 : 2.3 : 3.7 : 45 respectively. The activation parameters are similar for all the alcohols. Hammett acidity plots give slopes of c. 0.8 for the diols and of 1 for butan-2-ol. These variations in these kinetic parameters are discussed in terms of whether hydroxyl group substitution in butan-2-ol affects the mechanism of its reaction in these circumstances.

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