Synthesis and electron-transfer efficiency of oligopeptide-bridged donor–acceptor molecules

Author(s):  
Hitoshi Tamiaki ◽  
Kazuhiro Maruyama
2008 ◽  
Vol 07 (04) ◽  
pp. 869-877 ◽  
Author(s):  
YI ZHAO

Feynman and Vernon path integral approach is adopted to investigate electron transfer dynamics in donor–bridge–acceptor molecules under dissipative environments. Especially, we focus on the solvent effect on the superexchange process of electron transfer. The results reveal that at high enough bridge energies or low enough temperature, electron can transfer with a superexchange mechanism no matter whether solvent is incorporated or not. However, the superexchange changes from coherent to incoherent limits when the dissipative strength increases, and electron transfer rates are much dependent on the dissipative strength.


2006 ◽  
Vol 110 (41) ◽  
pp. 20258-20262 ◽  
Author(s):  
Randall H. Goldsmith ◽  
Michael R. Wasielewski ◽  
Mark A. Ratner

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