Radiating composite stars with electromagnetic fields

We derive the junction conditions for a general spherically symmetric radiating star with an electromagnetic field across a comoving surface. The interior consists of a charged composite field containing barotropic matter, a null dust and a null string fluid. The exterior atmosphere is described by the generalised Vaidya spacetime. We generate the boundary condition at the stellar surface showing that the pressure is determined by the interior heat flux, anisotropy, null density, charge distribution and the exterior null string density. A new physical feature that arises in our analysis is that the surface pressure depends on the internal charge distribution for generalised Vaidya spacetimes. It is only in the special case of charged Vaidya spacetimes that the matching interior charge distribution is equal to the exterior charge at the surface as measured by an external observer. Previous treatments, for neutral matter and charged matter, arise as special cases in our treatment of composite matter.

A benzothiazole-based fluorescence turn-on sensor for copper(II)

A new benzothiazole-based chemosensor BTN (1-((Z)-(((E)-3-methylbenzo[d]thiazol-2(3H)-ylidene)hydrazono)methyl)naphthalen-2-ol) was synthesized for the detection of Cu2+. BTN could detect Cu2+ with “off-on” fluorescent response from colorless to yellow irrespective of presence of other cations. Limit of detection for Cu2+ was determined to be 3.3 µM. Binding ratio of BTN and Cu2+ turned out to be a 1:1 with the analysis of Job plot and ESI-MS. Sensing feature of Cu2+ by BTN was explained with theoretical calculations, which might be owing to internal charge transfer and chelation-enhanced fluorescence processes.

Ultrafast synthesis of near-zero-cost S-doped Ni(OH)2 on C3N5 under ambient conditions with enhanced photocatalytic activity

2D S–Ni(OH)2 is facially planted on 2D C3N5 at room temperature in 30 minutes via a reaction between Ni(NO3)2 and Na2S in aqueous solution. Due to quick internal charge transfer efficiency, the hybrid is highly efficient for photocatalytic H2 production.