scholarly journals Research progress of low-temperature heat recovery technology in sulfuric acid production

2020 ◽  
Vol 194 ◽  
pp. 01001
Author(s):  
Jianfang Zong ◽  
Liang Sun ◽  
Huiting Guo ◽  
Fei Fang

Low-temperature waste heat refers to the sum of the heat degraded and transferred to the dry absorption process after the high- and medium-temperature heat is recovered in the conversion process in the conventional sulfuric acid production plant, as well as the sulfuric acid formation heat, steam condensation heat and sulfuric acid dilution heat generated in the dry absorption process. It is of great practical significance to rationally develop and utilize the low-temperature waste heat. This paper introduces the development of traditional waste heat recovery technology and low-temperature heat recovery technology for sulfur-based sulfuric acid production. It also expounds the principle, process technology and main equipment of developing low-temperature heat recovery technology for sulfuric acid production plants at home and abroad, and summarizes the low-temperature heat recovery technology for sulfuric acid production plants.

2017 ◽  
Vol 14 (1) ◽  
pp. 19-26 ◽  
Author(s):  
Lingling Bao ◽  
Jiaying Wang ◽  
Jinggang Wang ◽  
Zheng Yu

Purpose Currently, China is the largest coal producer and consumer in the world. Underground mining is the main practice. In the process of deep mining, large amounts of low-temperature waste heat are available such as in the mine return air (MRA), mine water (MW), bathing waste water (BWW), etc. Without recycling, the low-temperature waste heat is discharged directly into the atmosphere or into the drainage system. The temperature range of the MRA is about 15-25°C, the relative humidity (RH) of the MRA is above 90 per cent, the temperature range of MW is about 18-20°C and the temperature of the BWW is about 30°C. All of the above parameters are relatively stable throughout the year, and thus MRA, MW and BWW are proper low-temperature heat sources for water source heat pump (WSHP) systems. The study aims to introduce the schemes for recycling the different waste heat sources and the relevant key equipment and technology of each waste heat recycle system; analyze the heat recovery performances of the MRA heat recovery technology; and compare the economies between the MRA heat recovery system and the traditional system. Design/methodology/approach Based on the WSHP system, heat and mass transfer efficiencies were calculated and analyzed, the outlet air velocity diffusion of the heat and mass transfer units and the parameters including air flow rate, the MRA’s dry bulb temperatures and wet bulb temperatures at inlet and outlet of MRA heat exchanger were tested. Then, it was assessed whether this system can be applied to an actual construction. An actual reconstructive project of MRA heat recovery system is taken as an example, where the cost-saving effects of heat recovery of mine waste heat sources system are analyzed. Findings Analysis of field test reveals that when heat transfer is stable, heat transfer capacity can be achieved: 957.6 kW in summer, 681 kW in winter and a large amount of heat was recycled. In an economic analysis, by comparing initial investment and 10 years’ operation cost with the traditional boiler and central air conditioning system, the results show that although the MRA system’s initial investment is high, this system can save CNY 6.26m in 10 years. Originality/value MRA has a large amount of air volume and temperature that is constant throughout the year, and hence is a good low-temperature heat source for the WSHP system. It can replace boiler heating in winter and central air conditioning refrigeration in summer. The study reveals that this technology is feasible, and has good prospects for development.


2014 ◽  
Vol 16 (4) ◽  
Author(s):  
B. Duysebaev ◽  
A. Abramov ◽  
S. Berstenev ◽  
N. Ryspanov ◽  
A.Y. Sokolov ◽  
...  

<p>The possibility and effectiveness of using sulfur dioxide and hydrogen sulfide as the fuel in low-temperature fuel cells at the sulfuric acid production site has been investigated. A fuel cell has been designed and constructed using palladium as a catalyst, which enables conversion of the energy of oxidation of sulfur dioxide and hydrogen sulfide to the electric energy. The experimental data showed that the use of hydrogen sulfide and sulfur dioxide as a fuel allows achieving the power of 1.0 and 0.5 mW, respectively. The <br />comparative studies with the use of hydrogen in the same fuel cell resulted in the power of about 2.0 mW, i.e. the use of hydrogen sulfide delivers a performance comparable with that of the hydrogen. The processes of oxidizing of the sulfur containing gases are used in our company in production of sulfuric acid. Oxidation <br />of these gases conducted using the conventional technological processes. The use of these processes to produce energy as a byproduct could be an attractive way to reduce the energy consumption of the whole process. Considering the relatively high power obtained in this work for the sulfur containing gases fed fuel <br />cells, the substitution of conventional oxidation of sulfur containing gases in this technological chain by the fuel cell oxidation, and by-producing the electric energy, could be very profitable for the energy efficiency enhancement of the main production process. In the future work, the design and development of fuel cell catalysts and membranes to enhance the performances of sulfur containing fuel cells will be significant</p>


Entropy ◽  
2019 ◽  
Vol 21 (12) ◽  
pp. 1197
Author(s):  
Kai-Yuan Lai ◽  
Yu-Tang Lee ◽  
Miao-Ru Chen ◽  
Yao-Hsien Liu

Low-temperature heat utilization can be applied to waste heat from industrial processes or renewable energy sources such as geothermal and ocean energy. The most common low-temperature waste-heat recovery technology is the organic Rankine cycle (ORC). However, the phase change of ORC working fluid for the heat extraction process causes a pinch-point problem, and the heat recovery cannot be efficiently used. To improve heat extraction and power generation, this study explored the cycle characteristics of the trilateral flash cycle (TFC) in a low-temperature heat source. A pinch-point-based methodology was developed for studying the optimal design point and operating conditions and for optimizing working fluid evaporation temperature and mass flow rate. According to the simulation results, the TFC system can recover more waste heat than ORC under the same operating conditions. The net power output of the TFC was approximately 30% higher than ORC but at a cost of higher pump power consumption. Additionally, the TFC was superior to ORC with an extremely low-temperature heat source (<80 °C), and the ideal efficiency was approximately 3% at the highest work output condition. The TFC system is economically beneficial for waste-heat recovery for low-temperature heat sources.


2021 ◽  
Vol 13 (9) ◽  
pp. 5223
Author(s):  
Miriam Benedetti ◽  
Daniele Dadi ◽  
Lorena Giordano ◽  
Vito Introna ◽  
Pasquale Eduardo Lapenna ◽  
...  

The recovery of waste heat is a fundamental means of achieving the ambitious medium- and long-term targets set by European and international directives. Despite the large availability of waste heat, especially at low temperatures (<250 °C), the implementation rate of heat recovery interventions is still low, mainly due to non-technical barriers. To overcome this limitation, this work aims to develop two distinct databases containing waste heat recovery case studies and technologies as a novel tool to enhance knowledge transfer in the industrial sector. Through an in-depth analysis of the scientific literature, the two databases’ structures were developed, defining fields and information to collect, and then a preliminary population was performed. Both databases were validated by interacting with companies which operate in the heat recovery technology market and which are possible users of the tools. Those proposed are the first example in the literature of databases completely focused on low-temperature waste heat recovery in the industrial sector and able to provide detailed information on heat exchange and the technologies used. The tools proposed are two key elements in supporting companies in all the phases of a heat recovery intervention: from identifying waste heat to choosing the best technology to be adopted.


2019 ◽  
Vol 27 (10) ◽  
pp. 2227-2237 ◽  
Author(s):  
Li Xia ◽  
Renmin Liu ◽  
Yiting Zeng ◽  
Peng Zhou ◽  
Jingjing Liu ◽  
...  

Author(s):  
L. Lopera ◽  
C. Nieto ◽  
A. C. Escudero ◽  
C. A. Bustamante ◽  
M. C. Fernández

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