Asymmetric, Light-Mediated Radical Sulfinyl-Smiles Rearrangement

Synfacts ◽  
2021 ◽  
Vol 17 (07) ◽  
pp. 0783
Keyword(s):  
Smiles Rearrangement

Several Species of Nucleophiles in the Smiles Rearrangement

2017 ◽  
Vol 21 (16) ◽  
Author(s):  
Ali Ramazani ◽  
Farzaneh Moradnia ◽  
Hamideh Aghahosseini ◽  
Ilnaz Abdolmaleki
Keyword(s):  
Smiles Rearrangement

BENZOTHIAZEPINONES, RELATED COMPOUNDS, AND THE SMILES REARRANGEMENT

1979 ◽  
Vol 7 (1) ◽  
pp. 41-45 ◽  
Author(s):  
Edward Y Chan ◽  
Ronald G. Crampton ◽  
Leallyn B. Clapp
Keyword(s):  
Smiles Rearrangement ◽  
Related Compounds

scholarly journals Synthesis of new hybrid 1,4-thiazinyl-1,2,3-dithiazolyl radicals via Smiles rearrangement

2017 ◽  
Vol 46 (46) ◽  
pp. 16004-16008 ◽  
Author(s):  
Petra Vasko ◽  
Juha Hurmalainen ◽  
Akseli Mansikkamäki ◽  
Anssi Peuronen ◽  
Aaron Mailman ◽  
...  
Keyword(s):  
Smiles Rearrangement ◽  
Spin Densities

New hybrid 1,4-thiazine-1,2,3-dithiazolylium salts were prepared via Smiles rearrangement. The cations can be readily reduced to the corresponding stable neutral radicals with delocalised spin densities.

Effect of α-cyclodextrin complexation on a general-base-catalyzed photo-smiles rearrangement

1986 ◽  
Vol 27 (27) ◽  
pp. 3103-3106 ◽  
Author(s):  
Gene G. Wubbels ◽  
Bradley R. Sevetson ◽  
Steven N. Kaganove
Keyword(s):  
Smiles Rearrangement ◽  
General Base ◽  
Cyclodextrin Complexation

ChemInform Abstract: Novel Syntheses of 3-Anilino-pyrazin-2(1H)-ones and 3-Anilino-quinoxalin-2(1H)-ones via Microwave-Mediated Smiles Rearrangement.

ChemInform ◽  
2008 ◽  
Vol 39 (26) ◽  
Author(s):  
F. Christopher Bi ◽  
Gary E. Aspnes ◽  
Angel Guzman-Perez ◽  
Daniel P. Walker
Keyword(s):  
Smiles Rearrangement

scholarly journals Amidines. V. Smiles rearrangement of N1-(p-nitrobenzenesulfonyl)-N1,N2-diarylacetamidines.

1990 ◽  
Vol 38 (5) ◽  
pp. 1373-1378 ◽  
Author(s):  
Machiko ONO ◽  
Ichiro ARAYA ◽  
Shinzo TAMURA
Keyword(s):  
Smiles Rearrangement

scholarly journals The Truce–Smiles rearrangement and related reactions: a review

2017 ◽  
Vol 95 (5) ◽  
pp. 483-504 ◽  
Author(s):  
Anna R.P. Henderson ◽  
Joel R. Kosowan ◽  
Tabitha E. Wood
Keyword(s):  
Nucleophilic Aromatic Substitution ◽  
Future Research ◽  
Tandem Reaction ◽  
Aromatic Substitution ◽  
Smiles Rearrangement ◽  
Research Directions ◽  
Reaction Method ◽  
Design Variables ◽  
Leaving Group ◽  
Future Research Directions

The Truce–Smiles rearrangement is an X → C aryl migration reaction that is achieved by an intramolecular nucleophilic aromatic substitution pathway. The reaction exhibits a wide substrate scope with respect to a migrating aryl ring and leaving group, appearing in many different tandem reaction sequences, to achieve a wide variety of product outcomes. We present an extensive survey of reported examples of the Truce–Smiles rearrangement from the chemistry literature (1950s until present) organized by various substrate design variables or aspects of the reaction method. Present deficiencies in our understanding of the reaction are identified with recommendations for future research directions and useful developments in the application of the reaction are celebrated.

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