NMR Studies of Aqueous Electrolyte Solutions. IV. Hydration Numbers of Strong Electrolytes Determined from Temperature Effects on Proton Shifts

1971 ◽  
Vol 54 (1) ◽  
pp. 178-181 ◽  
Author(s):  
Brother Ferdinand J. Vogrin ◽  
Paul S. Knapp ◽  
William L. Flint ◽  
Arthur Anton ◽  
Gerald Highberger ◽  
...  
Keyword(s):  
Temperature Effects ◽  
Aqueous Electrolyte ◽  
Electrolyte Solutions ◽  
Hydration Numbers ◽  
Nmr Studies ◽  
Aqueous Electrolyte Solutions ◽  
Strong Electrolytes

Interpretation of properties of aqueous electrolyte solutions in terms of hydration and incomplete dissociation

1988 ◽  
Vol 53 (4) ◽  
pp. 686-696 ◽  
Author(s):  
Rajalakshmi Heyrovská
Keyword(s):  
Aqueous Solutions ◽  
Aqueous Electrolyte ◽  
Electrolyte Solutions ◽  
Hydration Numbers ◽  
Concentrated Aqueous Solutions ◽  
Strong Electrolytes ◽  
Strong Acids ◽  
Degrees Of Dissociation ◽  
Concentration Cells ◽  
Existing Data

The existing data on the vapour pressures, densities and e.m.f.s of concentration cells of dilute and concentrated aqueous solutions of strong electrolytes have been interpreted in terms of hydration and incomplete dissociation. Hydration numbers and degrees of dissociation have been presented for several 1 : 1 strong electrolytes at 25 °C. Thus the actual ionic concentrations of strong acids, bases and salts, hitherto inaccessible, have now been made available.

Erratum: NMR Studies of Aqueous Electrolyte Solutions

1967 ◽  
Vol 47 (1) ◽  
pp. 347-348 ◽  
Author(s):  
Edmund R. Malinowski ◽  
Paul S. Knapp ◽  
Bernice Feuer
Keyword(s):  
Aqueous Electrolyte ◽  
Electrolyte Solutions ◽  
Nmr Studies ◽  
Aqueous Electrolyte Solutions

Promoting Nitrogen Electroreduction to Ammonia with Bismuth Nanocrystals and Potassium Cations in Water

2020 ◽  
Author(s):  
Jaecheol Choi ◽  
Hoang-Long Du ◽  
Manjunath Chatti ◽  
Bryan H. R. Suryanto ◽  
Alexandr Simonov ◽  
...  
Keyword(s):  
Electrocatalytic Activity ◽  
Aqueous Electrolyte ◽  
Electrolyte Solutions ◽  
Reduction Reaction ◽  
Nitrogen Reduction ◽  
Aqueous Electrolyte Solutions

We demonstrate that bismuth exhibits no measurable electrocatalytic activity for the nitrogen reduction reaction to ammonia in aqueous electrolyte solutions, contrary to several recent reports on the highly impressive rates of Bi-catalysed electrosynthesis of NH<sub>3</sub> from N<sub>2</sub>.

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