Infrared and Raman Spectra of Substituted Hydrazines. III Symmetrical Dimethylhydrazine

Available data on infrared and Raman spectra of S4N4 in solid state and solutions have been verified and completed. On the basis of normal coordinate analysis an attempt has been made to define with more precision the interpretation of vibration spectra of this compound given in earlier reports.

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Vibrational spectra of aquadioxotetra; peroxodivanadates(V) M2[V2O2(O2)4(H2O)]·xH2O (M = N(CH3)4, Cs)

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19901485 ◽

1990 ◽

Vol 55 (6) ◽

pp. 1485-1490 ◽

Cited By ~ 4

Author(s):

Peter Schwendt ◽

Milan Sýkora

Keyword(s):

Raman Spectra ◽

Vibrational Spectra ◽

Normal Coordinate Analysis ◽

Force Constants ◽

Infrared And Raman Spectra ◽

Empirical Correlations ◽

Normal Coordinate ◽

Bond Lengths ◽

Stretching Vibrations

The infrared and Raman spectra of M2[V2O2(O2)4(H2O)]·xH2O and M2[V2O2(O2)4(D2O)]·xD2O (M = N(CH3)4, Cs) were measured. In the region of the vanadium-oxygen stretching vibrations, the spectra were interpreted based on normal coordinate analysis, employing empirical correlations between the bond lengths and force constants.

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Infrared and Raman Spectra, conformations,ab initio calculations and spectral assignments of 1,3-disilabutane (SiH3CH2SiH2CH3)

Journal of Raman Spectroscopy ◽

10.1002/jrs.1745 ◽

2007 ◽

Vol 38 (9) ◽

pp. 1159-1173 ◽

Cited By ~ 7

Author(s):

Gamil A. Guirgis ◽

Paul M. Mazzone ◽

Daniel N. Pasko ◽

Peter Klaeboe ◽

Anne Horn ◽

...

Keyword(s):

Ab Initio Calculations ◽

Ab Initio ◽

Raman Spectra ◽

Infrared And Raman Spectra

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ChemInform Abstract: INFRARED AND RAMAN SPECTRA, VIBRATIONAL ASSIGNMENT AND BARRIERS TO INTERNAL ROTATION FOR METHYLDISILYLAMINE

Chemischer Informationsdienst ◽

10.1002/chin.197804050 ◽

1978 ◽

Vol 9 (4) ◽

Author(s):

J. R. DURIG ◽

P. J. COOPER

Keyword(s):

Internal Rotation ◽

Raman Spectra ◽

Infrared And Raman Spectra ◽

Vibrational Assignment ◽

Barriers To Internal Rotation

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CONFORMATIONAL EQUILIBRIA IN OPEN-CHAIN α,β-UNSATURATED KETONES

Canadian Journal of Chemistry ◽

10.1139/v61-294 ◽

1961 ◽

Vol 39 (11) ◽

pp. 2225-2235 ◽

Cited By ~ 54

Author(s):

K. Noack ◽

R. Norman Jones

Keyword(s):

Raman Spectra ◽

Equilibrium Mixture ◽

Infrared And Raman Spectra ◽

Temperature Dependent ◽

Trans Form ◽

Open Chain ◽

Unsaturated Ketones ◽

Conformational Isomers ◽

Alkyl Substitution ◽

Conformational Equilibria

The infrared and Raman spectra of trans-Δ3-penten-2-one have been measured over the temperature range +30° to −75° and +85° to +5° respectively. The temperature-dependent changes observed in the spectra indicate that this ketone exists as an equilibrium mixture of s-cis and s-trans conformational isomers in the liquid state. The s-trans form is the more stable and is present exclusively in the crystalline solid.Similar measurements have been carried out on Δ3-buten-2-one. The infrared and Raman spectra of this ketone also exhibit temperature effects that can be explained by a similar equilibrium, though the evidence is not as conclusive as for trans-Δ3-penten-2-one.The influence of alkyl substitution at the α- and β-carbon atoms on the relative stability of the s-cis and s-trans forms of α,β-unsaturated ketones is discussed.

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