The bimolecular thermal rate coefficient calculated from Monte Carlo integration over relative velocity and orbital angular momentum

1976 ◽  
Vol 65 (11) ◽  
pp. 5023-5024 ◽  
Author(s):  
R. N. Porter ◽  
D. L. Thompson

Consideration is given to the calculation of the rate coefficient of processes of the type A + + B + C → AB + + C. Classical mechanics is used. The impulse approximation is adopted and hard-sphere interactions are taken to describe C – A + and C – B collisions. Formulae are derived for the rate coefficients of binary collisions giving specified changes in the internal energy of the associating pair (without reference to their orbital angular momentum) and also of binary collisions giving specified changes in both the internal energy and in the square of the orbital angular momentum. By using quasi-equilibrium statistical theory, the rate co­efficient for three-body ion-neutral association is expressed in terms of either set of binary rate coefficients. Computations are carried out only Hg + + Hg + He → Hg + 2 + He. As expected, the predicted rate co­efficient is too high if specific account is not taken of the orbital angular momentum. If such account is taken excellent agreement is obtained with a measurement at 370 K made by Biondi (1953, 1972, private com­munication). The rate coefficient falls off slowly as the temperature is increased.


Author(s):  
Ryohei Yamagishi ◽  
Hiroto Otsuka ◽  
Ryo Ishikawa ◽  
Akira Saitou ◽  
Hiroshi Suzuki ◽  
...  

2020 ◽  
Vol 117 (19) ◽  
pp. 191101
Author(s):  
Wenpu Geng ◽  
Yiqiao Li ◽  
Yuxi Fang ◽  
Yingning Wang ◽  
Changjing Bao ◽  
...  

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Zhe Zhao ◽  
Runzhou Zhang ◽  
Hao Song ◽  
Kai Pang ◽  
Ahmed Almaiman ◽  
...  

AbstractOrbital-angular-momentum (OAM) multiplexing has been utilized to increase the channel capacity in both millimeter-wave and optical domains. Terahertz (THz) wireless communication is attracting increasing attention due to its broadband spectral resources. Thus, it might be valuable to explore the system performance of THz OAM links to further increase the channel capacity. In this paper, we study through simulations the fundamental system-degrading effects when using multiple OAM beams in THz communications links under atmospheric turbulence. We simulate and analyze the effects of divergence, turbulence, limited-size aperture, and misalignment on the signal power and crosstalk of THz OAM links. We find through simulations that the system-degrading effects are different in two scenarios with atmosphere turbulence: (a) when we consider the same strength of phasefront distortion, faster divergence (i.e., lower frequency; smaller beam waist) leads to higher power leakage from the transmitted mode to neighbouring modes; and (b) however, when we consider the same atmospheric turbulence, the divergence effect tends to affect the power leakage much less, and the power leakage increases as the frequency, beam waist, or OAM order increases. Simulation results show that: (i) the crosstalk to the neighbouring mode remains < − 15 dB for a 1-km link under calm weather, when we transmit OAM + 4 at 0.5 THz with a beam waist of 1 m; (ii) for the 3-OAM-multiplexed THz links, the signal-to-interference ratio (SIR) increases by ~ 5–7 dB if the mode spacing increases by 1, and SIR decreases with the multiplexed mode number; and (iii) limited aperture size and misalignment lead to power leakage to other modes under calm weather, while it tends to be unobtrusive under bad weather.


2021 ◽  
Vol 126 (11) ◽  
Author(s):  
Justin S. Woods ◽  
Xiaoqian M. Chen ◽  
Rajesh V. Chopdekar ◽  
Barry Farmer ◽  
Claudio Mazzoli ◽  
...  

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