Dipolar interactions between NH3molecules trapped in solid argon. I. Kinetics of the nuclear spin species conversion

1993 ◽  
Vol 98 (9) ◽  
pp. 6827-6834 ◽  
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B. Gauthier‐Roy ◽  
L. Abouaf‐Marguin ◽  
P. Boissel

1993 ◽  
Vol 98 (9) ◽  
pp. 6835-6842 ◽  
Author(s):  
P. Boissel ◽  
B. Gauthier‐Roy ◽  
L. Abouaf‐Marguin


1982 ◽  
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M. Goldman ◽  
J.F. Jacquinot


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James E. Kohl ◽  
Myron G. Semack ◽  
David White




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H. P. Hopkins ◽  
R. F. Curl ◽  
Kenneth S. Pitzer


2000 ◽  
Vol 331 (2-4) ◽  
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Andreas Langenscheidt ◽  
Hermann Meyer ◽  
Armin Schweig




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George E. Ewing


1974 ◽  
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B. C. Sanctuary

For symmetric top molecules the role of nuclear spin symmetry is included in the derivation of the nuclear magnetic relaxation rate. It is assumed that this is dominated by a spin-rotation mechanism. Of the three nuclear spin species which exist for ZX3Y' symmetric tops, it is found that the "zero frequency" K = −1 to +1 term results in two of the species relaxing with a different rate from the third. The difference, which allows a direct NMR evaluation of the relative values of [Formula: see text] and [Formula: see text], is enhanced at low temperatures.



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