Resolved high Rydberg spectroscopy of benzene⋅rare gas van der Waals clusters: Enhancement of spin–orbit coupling in the radical cation by an external heavy atom

1999 ◽  
Vol 110 (12) ◽  
pp. 5589-5599 ◽  
Author(s):  
Klaus Siglow ◽  
Robert Neuhauser ◽  
Hans Jürgen Neusser
1997 ◽  
Vol 119 (6) ◽  
pp. 1323-1327 ◽  
Author(s):  
Shinya Sasaki ◽  
Akio Katsuki ◽  
Kimio Akiyama ◽  
Shozo Tero-Kubota

2019 ◽  
Vol 532 (2) ◽  
pp. 1900344 ◽  
Author(s):  
Enrico Rossi ◽  
Christopher Triola

1999 ◽  
Vol 248 (2-3) ◽  
pp. 233-246 ◽  
Author(s):  
N.V. Korol'kova ◽  
V.G. Klimenko ◽  
T.A. Kir'yanova ◽  
S.A. Serov ◽  
E.A. Gastilovich

1976 ◽  
Vol 31 (7) ◽  
pp. 748-753
Author(s):  
J. Friedrich ◽  
G. Weinzierl ◽  
F. Dörr

Abstract The influence of ethylhalogenes on the polarization of the phosphorescence of naphthalene was studied by means of the photoselection technique. It is shown that with increasing concentration and with increasing nuclear charge of the heavy atom the phosphorescence of naphthalene becomes increasingly depolarized. The influence of the external heavy atom on the Tx- and Tz- substate is stronger than on the Ty-substate. From the concentration dependence of the depolarizatign conclusions concerning the mechanism of the external spin-orbit-coupling are drawn. The dirept spin-orbit-coupling mechanism is ruled out. In the model discussed the variation of the external heavy atom effect with the intermolecular distance is related to overlap integrals.


2017 ◽  
Vol 140 ◽  
pp. 346-353 ◽  
Author(s):  
Cristian A.M. Salla ◽  
Hugo C. Braga ◽  
Renata da S. Heying ◽  
Jefferson S. Martins ◽  
Welber G. Quirino ◽  
...  

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