Vibrational dynamics of hydrogen-bonded HCl-diethyl ether complexes

2000 ◽  
Vol 112 (11) ◽  
pp. 5127-5132 ◽  
Author(s):  
I. A. M. E. Giebels ◽  
M. A. F. H. van den Broek ◽  
M. F. Kropman ◽  
H. J. Bakker
2003 ◽  
Vol 103-104 ◽  
pp. 173-176 ◽  
Author(s):  
C. Branca ◽  
S. Magazù ◽  
F. Migliardo ◽  
G. Romeo

Author(s):  
Thomas Elsaesser ◽  
Karsten Heyne ◽  
Nils Huse ◽  
Erik T.J. Nibbering

2013 ◽  
Vol 69 (12) ◽  
pp. m673-m674
Author(s):  
Alastair J. Nielson ◽  
Chaohong Shen ◽  
Joyce M. Waters

The title adduct, [TiCl2(C23H30O2)(C13H10O]·0.5C13H10·C4H10O, is a monomer with a trigonal–bypyramidal coordination sphere of the TiIVatom in which the ligand O atoms of the bidentate diphenolate anion are located in both apical and equatorial positions. Chloride ligands occupy the remaining two equatorial sites of the trigonal bypyramid with the fluoren-9-ol O atom occupying the other apical site. The hydroxy group H atom of this latter group is hydrogen bonded to an O atom of a non-coordinating diethyl ether molecule. The title compound also contains a further fluorene solvent molecule, which lies across a centre of symmetry and which is equally disordered over an inversion centre.


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