Cobalt(II) Perfluorooctane Sulfonate Catalyzed Highly Efficient Aerobic Oxidation of Alcohols in Fluorous Biphasic Systems

2006 ◽  
Vol 59 (5) ◽  
pp. 349 ◽  
Author(s):  
Wen-Bin Yi ◽  
Chun Cai
Keyword(s):  
Molecular Oxygen ◽  
Atmospheric Pressure ◽  
Carbonyl Compounds ◽  
Aerobic Oxidation ◽  
Perfluorooctane Sulfonate ◽  
Highly Efficient ◽  
Oxidation Of Alcohols ◽  
Biphasic Systems

Cobalt(ii) perfluorooctane sulfonate (Co(OPf)2) acts as a novel homogeneous pre-catalyst for the oxidation of various types of alcohols to carbonyl compounds under atmospheric pressure of molecular oxygen in fluorous biphasic systems. By simple separation of the fluorous phase, which contains only pre-catalyst, the reaction can be repeated several times.

Modified Markó’s aerobic oxidation of alcohols under atmospheric pressure with air or molecular oxygen at room temperature

2012 ◽  
Vol 53 (44) ◽  
pp. 5880-5882 ◽  
Author(s):  
Takeshi Nishii ◽  
Tomomi Ouchi ◽  
Aya Matsuda ◽  
Yuka Matsubara ◽  
Yuuko Haraguchi ◽  
...  
Keyword(s):  
Molecular Oxygen ◽  
Atmospheric Pressure ◽  
Room Temperature ◽  
Aerobic Oxidation ◽  
Oxidation Of Alcohols

Highly efficient sulfonated-polystyrene–Cu(II)@Cu3(BTC)2 core–shell microsphere catalysts for base-free aerobic oxidation of alcohols

2015 ◽  
Vol 3 (8) ◽  
pp. 4266-4273 ◽  
Author(s):  
Xiaowei Zhang ◽  
Wenjun Dong ◽  
Yi Luan ◽  
Mu Yang ◽  
Li Tan ◽  
...  
Keyword(s):  
Molecular Oxygen ◽  
Aerobic Oxidation ◽  
Core Shell ◽  
Sulfonated Polystyrene ◽  
Highly Efficient ◽  
Oxidation Of Alcohols

A novel core–shell SPS–Cu(II)@Cu3(BTC)2 catalyst was developed for the aerobic oxidation of alcohols by molecular oxygen under base-free conditions.

Efficient and selective aerobic oxidation of alcohols catalysed by MOF-derived Co catalysts

2016 ◽  
Vol 18 (4) ◽  
pp. 1061-1069 ◽  
Author(s):  
Cuihua Bai ◽  
Aiqin Li ◽  
Xianfang Yao ◽  
Hongli Liu ◽  
Yingwei Li
Keyword(s):  
Heterogeneous Catalyst ◽  
Selective Oxidation ◽  
Atmospheric Pressure ◽  
Aerobic Oxidation ◽  
Co Catalysts ◽  
Highly Efficient ◽  
Neat Water ◽  
Oxidation Of Alcohols ◽  
Selective Aerobic Oxidation

A magnetic Co-based heterogeneous catalyst derived from MOFs is highly efficient in selective oxidation of alcohols in neat water under an atmospheric pressure of air and base-free conditions.

ChemInform Abstract: Modified Marko′s Aerobic Oxidation of Alcohols under Atmospheric Pressure with Air or Molecular Oxygen at Room Temperature.

ChemInform ◽  
2013 ◽  
Vol 44 (6) ◽  
pp. no-no
Author(s):  
Takeshi Nishii ◽  
Tomomi Ouchi ◽  
Aya Matsuda ◽  
Yuka Matsubara ◽  
Yuuko Haraguchi ◽  
...  
Keyword(s):  
Molecular Oxygen ◽  
Atmospheric Pressure ◽  
Room Temperature ◽  
Aerobic Oxidation ◽  
Oxidation Of Alcohols
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