Nuclear magnetic resonance studies of Lewis acid-base interaction. I. Base adducts of Bis(ethylxanthato)nickel(II)

1974 ◽  
Vol 27 (1) ◽  
pp. 213 ◽  
Author(s):  
Yau Yan. Lim

The interaction between bis(ethylxanthato)nickel(11) and pyridine and 4-picoline in nitrobenzene was studied by N.M.R. spectroscopy at 34�C. The 1 : 2 equilibrium constants and proton n.m.r, isotropic contact shifts were obtained. The electron spin delocalization mechanism in the 1 : 2 adduct was discussed.

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