Regulation on tribological performance of tungsten-doped DLC coatings by Choline Chloride-Urea and -Thiourea Deep Eutectic Solvents

Solid-liquid composite lubrication system has attracted an increased interest for low friction and wear. Nevertheless, the effect of mechanical and surface properties of the solid materials, especially the mechanical and surface properties governed by doping elements, on the tribological performance solid-liquid composite lubrication system is still not well comprehended. Here, we reported the effect of W content on the mechanical and surface properties of W-DLC coatings as well as the tribological properties of W-DLC coatings under (choline chloride-urea and choline chloride-thiourea) deep eutectic solvents lubrication. Although the wear of W-DLC coatings under dry friction increases with W content, the wear under DESs is slight when coatings show excellent wettability to DESs or a DES-derived tribochemical film is formed. We demonstrate that the tribological behavior of W-DLC and DESs composite lubrication system is related to the mechanical properties of W-DLC coatings together with the contact angle and tribochemical interaction between DESs and W-DLC coatings.

Fretting tribological performance of DLC, TiAlN and DLC/TiAlN coatings deposited on carburized 18CrNi4A steel

To improve the fretting wear performance of 18CrNi4A steel, DLC, TiAlN and DLC/TiAlN coatings were deposited on the surface of carburized 18CrNi4A steel, respectively. The microstructure morphologies, chemical compositions, and mechanical properties of these coatings were evaluated. The fretting tribological properties of pad/flat contact pairs for carburized 18CrNi4A steel, DLC, TiAlN and DLC/TiAlN coatings were investigated in different lubricant environments including dry sliding and #RIPP 7254 aviation grease. The results show that DLC, TiAlN and DLC/TiAlN coatings deposited on the carburized 18CrNi4A steel surface can improve surface roughness, hardness, fracture toughness and resistance to plastic deformation. DLC, TiAlN and DLC/TiAlN coatings deposited on the surface of carburized 18CrNi4A steel can make the surface of the substrate have excellent fretting wear properties. DLC and DLC/TiAlN coatings have lower coefficient of friction and better fretting wear resistance than TiAlN coatings in dry sliding condition, and DLC/TiAlN coatings have the lowest wear rate in #RIPP 7254 grease lubrication condition. In addition, the wear mechanisms of carburized 18CrNi4A steel, DLC, TiAlN and DLC/TiAlN coatings in dry sliding and #RIPP 7254 aviation grease conditions were analyzed.

Metal matrix nanocomposites in tribology: Manufacturing, performance, and mechanisms

Metal matrix nanocomposites (MMNCs) become irreplaceable in tribology industries, due to their supreme mechanical properties and satisfactory tribological behavior. However, due to the dual complexity of MMNC systems and tribological process, the anti-friction and anti-wear mechanisms are unclear, and the subsequent tribological performance prediction and design of MMNCs are not easily possible: A critical up-to-date review is needed for MMNCs in tribology. This review systematically summarized the fabrication, manufacturing, and processing techniques for high-quality MMNC bulk and surface coating materials in tribology. Then, important factors determining the tribological performance (mainly anti-friction evaluation by the coefficient of friction (CoF) and anti-wear assessment with wear rate) in MMNCs have been investigated thoroughly, and the correlations have been analyzed to reveal their potential coupling/synergetic roles of tuning tribological behavior of MMNCs. Most importantly, this review combined the classical metal/alloy friction and wear theories and adapted them to give a (semi-)quantitative description of the detailed mechanisms of improved anti-friction and anti-wear performance in MMNCs. To guarantee the universal applications of these mechanisms, their links with the analyzed influencing factors (e.g., loading forces) and characteristic features like tribo-film have been clarified. This approach forms a solid basis for understanding, predicting, and engineering MMNCs’ tribological behavior, instead of pure phenomenology and experimental observation. Later, the pathway to achieve a broader application for MMNCs in tribo-related fields like smart materials, biomedical devices, energy storage, and electronics has been concisely discussed, with the focus on the potential development of modeling, experimental, and theoretical techniques in MMNCs’ tribological processes. In general, this review tries to elucidate the complex tribo-performances of MMNCs in a fundamentally universal yet straightforward way, and the discussion and summary in this review for the tribological performance in MMNCs could become a useful supplementary to and an insightful guidance for the current MMNC tribology study, research, and engineering innovations.