Classical density functional analysis of the ionic size effects on the properties of charge regulating electric double layers

2021 ◽  
pp. e1937737
Author(s):  
D. J. Prakash ◽  
L. Denoyer ◽  
R. Vangara ◽  
J. M. Baca ◽  
F. van Swol ◽  
...  
Keyword(s):  
Functional Analysis ◽  
Size Effects ◽  
Density Functional ◽  
Double Layers ◽  
Electric Double Layers ◽  
Ionic Size

scholarly journals Non-scaling behavior of electroosmotic flow in voltage-gated nanopores

2017 ◽  
Vol 19 (1) ◽  
pp. 450-457 ◽  
Author(s):  
Cheng Lian ◽  
Alejandro Gallegos ◽  
Honglai Liu ◽  
Jianzhong Wu
Keyword(s):  
Electrical Conductivity ◽  
Ion Transport ◽  
Pore Size ◽  
Size Effects ◽  
Electroosmotic Flow ◽  
Scaling Behavior ◽  
Double Layers ◽  
Electric Double Layers ◽  
Voltage Gated ◽  
Ionic Size

Ionic size effects and electrostatic correlations result in the non-monotonic dependence of the electrical conductivity on the pore size. For ion transport at a high gating voltage, the conductivity oscillates with the pore size due to a significant overlap of the electric double layers.

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