Theoretical Estimation of Acid Strength of Boron-Fluoride-Alcohol Complexes during Cationic Polymerization of Olefins

1995 ◽  
Vol 28 (1-4) ◽  
pp. 77-81 ◽  
Author(s):  
K. S. Minsker ◽  
V. A. Babkin ◽  
G. E. Zaikov
Keyword(s):  
Cationic Polymerization ◽  
Acid Strength ◽  
Theoretical Estimation ◽  
Boron Fluoride

Theoretical Estimation of Acid Strength of Fluorine Hydrogen-Boron Fluoride Complexes

2000 ◽  
Vol 47 (2-3) ◽  
pp. 513-518
Author(s):  
V. A. Babkina ◽  
Yu. A. Sangalov ◽  
K. S. Minsker ◽  
O. A. Ponomarev ◽  
R. G. Fedunov ◽  
...  
Keyword(s):  
Acid Strength ◽  
Theoretical Estimation ◽  
Boron Fluoride ◽  
Fluoride Complexes

CATIONIC POLYMERIZATION OF ETHYLENE OXIDE: IV. THE PROPAGATION REACTIONS

1960 ◽  
Vol 38 (10) ◽  
pp. 1967-1975 ◽  
Author(s):  
G. T. Merrall ◽  
G. A. Latrémouille ◽  
A. M. Eastham
Keyword(s):  
Molecular Weight ◽  
Ethylene Oxide ◽  
Cationic Polymerization ◽  
Chain Growth ◽  
Low Molecular Weight ◽  
Boron Fluoride

Studies of the boron-fluoride-catalyzed reaction of ethylene oxide with simple alcohols and low molecular weight polyglycols indicate three ways in which chain growth could occur, but only one of these is considered to be important after the initial stages of polymerization. The rate of disappearance of monomer reaches a maximum at a molecular weight of about 400. A mechanism is proposed to account for both polymerization and depolymerization and it is shown how equilibrium between these two reactions could result.

Cationic polymerization of 3-azidomethyl-3-methyloxetane in the presence of the boron fluoride etherate—ethylene glycol system

2010 ◽  
Vol 52 (3-4) ◽  
pp. 144-150 ◽  
Author(s):  
A. E. Tarasov ◽  
Ya. I. Estrin ◽  
O. M. Ol’khova ◽  
V. P. Lodygina ◽  
E. R. Badamshina
Keyword(s):  
Ethylene Glycol ◽  
Cationic Polymerization ◽  
Boron Fluoride

Cationic Polymerization of Styrene with Boron Fluoride-Etherate in Liquid Sulfur Dioxide.

1961 ◽  
Vol 64 (4) ◽  
pp. 717-720
Author(s):  
Niichiro TOKURA ◽  
Ryuzo ASAMI ◽  
Minoru MATSUDA ◽  
Haruo NEGISHI
Keyword(s):  
Sulfur Dioxide ◽  
Cationic Polymerization ◽  
Liquid Sulfur ◽  
Boron Fluoride

Epoxy-titania composites of cationic polymerization: synthesis conditions and properties

2015 ◽  
Vol 37 (4) ◽  
pp. 402-407
Author(s):  
S.V. Zhil’tsova ◽  
◽  
V.M. Mikhal’chuk ◽  
N.G. Leonova ◽  
R.I. Lyga ◽  
...  
Keyword(s):  
Cationic Polymerization ◽  
Synthesis Conditions
Sign in / Sign up

Export Citation Format

Share Document