Calculation of the specific heat for the first order, tricritical and second order phase transitions in NH4C1

1998 ◽  
Vol 67 (2) ◽  
pp. 399-412 ◽  
Author(s):  
H. Yurtseven ◽  
D. Kayişoğlu ◽  
W. F. Sherman
1995 ◽  
Vol 09 (18n19) ◽  
pp. 2247-2283 ◽  
Author(s):  
DANIELE FINOTELLO ◽  
GERMANO S. IANNACCHIONE

We review results of a high resolution systematic study of the specific heat for alkyl-cyanobiphenyl liquid crystals confined to the 0.2µm diameter cylindrical pores Anopore membranes. The nematic director alignment at the pore wall is varied from homeotropic to tangential by pore surface treatment. Several phenomena are uncovered by these studies which probed the weakly first order nematic to isotropic, the continuous smectic-A to nematic and the first order smectic-A to isotropic phase transitions. The specific heat is strongly dependent on the nematic director configuration, and confinement effects are remarkably distinct according to the order of the phase transition. The influence of elastic distortions and surface ordering and disordering effects are evident. Despite considerable departures from bulk behavior with regards to specific heat peaks size, rounding and width, and transition temperature shifts, a bulk-like critical behavior appears to be retained. The formation of smectic translational order within the pores is hindered for those liquid crystals that also possess a nematic phase. The average scalar order parameter temperature dependence is extracted from the specific heat results using a simplified Landau-de Gennes type of model, and is shown to be consistent with nuclear magnetic resonance results.


Open Physics ◽  
2009 ◽  
Vol 7 (3) ◽  
Author(s):  
Rachidi Yessoufou ◽  
Saliou Amoussa ◽  
Felix Hontinfinde

AbstractWe use exact recursion relations to study the magnetic properties of the half-integer mixed spin-5/2 and spin-3/2 Blume-Capel Ising ferromagnetic system on the two-fold Cayley tree that consists of two sublattices A and B. Two positive crystal-field interactions Δ1 and Δ2 are considered for the sublattice with spin-5/2 and spin-3/2 respectively. For different coordination numbers q of the Cayley tree sites, the phase diagrams of the model are presented with a special emphasis on the case q = 3, since other values of q reproduce similar results. First, the T = 0 phase diagram is illustrated in the (D A = Δ1/J,D B = Δ2/J) plane of reduced crystal-field interactions. This diagram shows triple points and coexistence lines between thermodynamically stable phases. Secondly, the thermal variation of the magnetization belonging to each sublattice for some coordination numbers q are investigated as well as the Helmoltz free energy of the system. First-order and second-order phase transitions are found. The second-order phase transitions become sharper and sharper when D A or D B increases. The first-order transitions only exist for some appropriate non-zero values of D A and/or D B. The corresponding transition lines never connect to the second-order transition lines. Thus, the non-existence of tricritical points remains one of the key features of the present model. The magnetic exponent β 0 of the model is estimated and found to be ¼ at small values of D A = D B = D and β 0 = ½ at large values of D. At intermediate values of D, there is a crossover region where the magnetic exponent displays interesting behaviours.


2015 ◽  
Vol 118 (14) ◽  
pp. 143902 ◽  
Author(s):  
The-Long Phan ◽  
T. A. Ho ◽  
T. V. Manh ◽  
N. T. Dang ◽  
C. U. Jung ◽  
...  

2012 ◽  
Vol 190 ◽  
pp. 331-334 ◽  
Author(s):  
P.E. Markin ◽  
N.V. Mushnikov ◽  
A.V. Proshkin ◽  
S.V. Belyaev

The X-ray diffraction and specific heat measurements have been performed for the ferromagnetic compounds (MnCo)1-xGe within the concentration range 0.02 x 0.035. The compounds possess the hexagonal Ni2In-type structure at elevated temperatures, while for the composition with x = 0.02 and 0.03 a spontaneous martensitic-type transition to the orthorhombic TiNiSi-type phase occurs at 283 and 221 K, respectively. We studied the entropy changes associated with the first-order structural transition and estimated the changes in magnetic, lattice, electronic entropies.


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