Gas Separation Performance of Polycarbonate Membranes Modified With Multifunctional Low Molecular‐Weight Additives

2006 ◽  
Vol 41 (9) ◽  
pp. 1813-1828 ◽  
Author(s):  
D. Şen ◽  
H. Kalıpçılar ◽  
L. Yılmaz
Author(s):  
P. C. Tan ◽  
D. Y. Yiauw ◽  
G. H. Teoh ◽  
S. C. Low ◽  
Z. A. Jawad

Various methods have been explored to improve the gas separation performance of polyimide membrane for more viable industrial commercialization. Generally, polyimide membrane can be synthesized via two different methods: chemical imidization and thermal imidization routes. Due to the markedly different membrane synthesis conditions, the influence of imidization methods on the gas transport properties of resulting membrane is worthy of investigation. The polyimide produced from two imidization methods was characterized for its molecular weight. In overall, the molecular weight of thermally imidized polyimide was higher than that of chemically imidized one except ODPA-6FpDA:DABA as it was prone to depropagation at high temperature. It was observed that the chemically imidized ODPA-6FpDA:DABA membrane possessed better gas separation performance than the thermally imidized counterpart. In particular, it showed 12 times higher CO2 permeability (19.21 Barrer) with CO2/N2 selectivity of 5. After crosslinking, the CO2/N2 selectivity of the polyimide membrane was further improved to 11.8 at 6 bar of permeation pressure.


2012 ◽  
Vol 53 (8) ◽  
pp. 1623-1630 ◽  
Author(s):  
Ywu-Jang Fu ◽  
Jung-Tsai Chen ◽  
Chun-Chieh Chen ◽  
Kuo-Sung Liao ◽  
Chien-Chieh Hu ◽  
...  

RSC Advances ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 5086-5095
Author(s):  
Shuli Wang ◽  
Xiaohua Tong ◽  
Chunbo Wang ◽  
Xiaocui Han ◽  
Sizhuo Jin ◽  
...  

Effect of substituents on the dihedral angle and chain packing plays a critical role in the enhancement in the gas separation performance of polymer membranes.


2021 ◽  
pp. 119401
Author(s):  
Moataz Ali El-Okazy ◽  
Liang Liu ◽  
Christopher P. Junk ◽  
Erich Kathmann ◽  
Whitney White ◽  
...  

Cellulose ◽  
2017 ◽  
Vol 24 (12) ◽  
pp. 5649-5656 ◽  
Author(s):  
Xiong-Fei Zhang ◽  
Yi Feng ◽  
Chaobo Huang ◽  
Yichang Pan ◽  
Jianfeng Yao

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